Počet nalezených dokumentů: 21
Publikováno od do

Gas sensors based on diamond heterostructures for air quality monitoring
Kočí, Michal; Szabó, Ondrej; Izsák, T.; Sojková, M.; Godzierz, M.; Wróbel, P.; Husák, M.; Kromka, Alexander
2024 - anglický
Currently, great emphasis is placed on air quality and the presence of pollutants. Attention is therefore focused on new gas-sensing materials enabling detection even at low (up to room) temperatures with sufficient response and short reaction time. Here, we investigate the suitability of H-NCD films and their heterostructures with MoS2, GO, rGO, SH-GO, or Au NPs for gas sensing applications. Electrical properties are measured for oxidizing gas NO2, reducing gas NH3, and chemical vapor of ethanol, and at temperatures varied from room temperature to 125 °C. In contrast to the individual forms of employed materials with limited response to the exposed gases, the HNCD heterostructures revealed better sensing properties. In particular, the Au NPs/H-NCD heterostructures revealed a higher response at 125 °C in contrast to H-NCD, MoS2/H-NCD had quite good response even at room temperature and GO/H-NCD revealed high sensitivity to chemical vapor, which further improved for the SH-GO/HNCD. Klíčová slova: gas sensors; nanocrystalline diamond; heterostructures; air quality monitoring Dokument je dostupný na externích webových stránkách.
Gas sensors based on diamond heterostructures for air quality monitoring

Currently, great emphasis is placed on air quality and the presence of pollutants. Attention is therefore focused on new gas-sensing materials enabling detection even at low (up to room) temperatures ...

Kočí, Michal; Szabó, Ondrej; Izsák, T.; Sojková, M.; Godzierz, M.; Wróbel, P.; Husák, M.; Kromka, Alexander
Fyzikální ústav, 2024

Surface changes induced by plasma treatment and high temperature annealing of silicon dioxide microparticles
Babčenko, Oleg; Remeš, Zdeněk; Beranová, Klára; Kolářová, Kateřina; Lörinc, J.; Prošek, Z.; Tesárek, P.
2024 - anglický
Due to the high surface to volume ratio, the particles’ surface properties modification defines its properties in general, which is crucial for their use. From this point of view, plasma processing or high temperature annealing can be considered as the universal techniques for efficient modification of materials in the form of powder. In this study, the silicon dioxide microparticles have been treated in a hydrogen, oxygen or vacuum by low temperature plasma or annealing. The change of SiO2 microparticles properties was investigated by photoluminescence spectroscopy at room and low temperature. High temperature annealing in hydrogen induced under UV excitation photoluminescence in the near UV and visible light indicating the change of defect states on the surface of the microparticles. We believe that observed findings clearly demonstrate useful method for analysis of SiO2 microparticles surface modification attractive also for fundamental research. Klíčová slova: silicon dioxide; plasma treatment; annealing; photoluminescence; measuring setup Dokument je dostupný na externích webových stránkách.
Surface changes induced by plasma treatment and high temperature annealing of silicon dioxide microparticles

Due to the high surface to volume ratio, the particles’ surface properties modification defines its properties in general, which is crucial for their use. From this point of view, plasma processing or ...

Babčenko, Oleg; Remeš, Zdeněk; Beranová, Klára; Kolářová, Kateřina; Lörinc, J.; Prošek, Z.; Tesárek, P.
Fyzikální ústav, 2024

Book of abstracts of the 1st outdoor seminar of the Department of Optical Materials: Advances in the new materials engineering and study
Buryi, Maksym; Král, Robert
2023 - anglický
The seminar is dedicated to the main activities of the department of Optical Materials, FZU - Institute of Physics of the Czech Academy of Sciences in the course of national and international collaborations. In particular, the advanced methods of the (nano)materials synthesis, fabrication, and characterization are presented and discussed in detail. The aim of the seminar is to establish more of the effective paths of communication and data exchange by creating and maintaining links among the teams of national and international experts in various fields of physical and chemical knowledge, both experimental and theoretical. Klíčová slova: nanomaterials; synthesis; data exchange Dokument je dostupný na externích webových stránkách.
Book of abstracts of the 1st outdoor seminar of the Department of Optical Materials: Advances in the new materials engineering and study

The seminar is dedicated to the main activities of the department of Optical Materials, FZU - Institute of Physics of the Czech Academy of Sciences in the course of national and international ...

Buryi, Maksym; Král, Robert
Fyzikální ústav, 2023

Book of Abstracts of the 32st Joint Seminar Development of Materials Science in Research and Education (DMSRE)
Kožíšek, Zdeněk; Král, Robert; Zemenová, Petra
2023 - anglický
Conference topics. Trends in the development of materials research. Information about the research programs of individual institutions. Results of materials research. Education of materials science at the universities. Information about equipment for preparation and characterization of materials.\n Klíčová slova: material sciences Dokument je dostupný na externích webových stránkách.
Book of Abstracts of the 32st Joint Seminar Development of Materials Science in Research and Education (DMSRE)

Conference topics. Trends in the development of materials research. Information about the research programs of individual institutions. Results of materials research. Education of materials science ...

Kožíšek, Zdeněk; Král, Robert; Zemenová, Petra
Fyzikální ústav, 2023

Development and measurement of gas sensors for room temperature applications
Kočí, Michal
2022 - anglický
Gas sensing properties of a nanocrystalline diamond with a hydrogen-terminated surface (H-terminated NCD) and a molybdenum disulphide (MoS2) are investigated as conductivity sensors with built-in interdigital metal electrode structures. The H-terminated NCD was prepared by plasma-enhanced chemical vapour deposition (PECVD), and the MoS2 by a carbide-free one-zone sulfurization method. The sensor's responses were measured for oxidizing (NO2) and reducing (NH3) gases by the same equipment and setup. The parameters of the tested sensors are compared and critically evaluated. Advantageously, the MoS2/H-terminated NCD heterostructure enhances the gas sensing response at room temperature compared to the H-terminated NCD and MoS2 layers. Klíčová slova: gas sensor; nanocrystalline diamond (NCD); transition metal dichalcogenide (TMD) Dokument je dostupný na externích webových stránkách.
Development and measurement of gas sensors for room temperature applications

Gas sensing properties of a nanocrystalline diamond with a hydrogen-terminated surface (H-terminated NCD) and a molybdenum disulphide (MoS2) are investigated as conductivity sensors with built-in ...

Kočí, Michal
Fyzikální ústav, 2022

Ab-initio study of surface energies and structural influece of vacancies in titanium nitride nanolayer
Lebeda, M.; Vlčák, P.; Veřtát, P.; Drahokoupil, Jan
2021 - anglický
The surface energies of 8 crystallographic planes and effects of nitrogen vacancies on the lattice parameter in rock salt-like structure of TiN (σ-TiN) were studied using ab-initio method of density functional theory (DFT) with the generalized gradient approximation functional (GGA) as parametrized by Perdex, Burke and Ernzerhof (PBE). The linear decrease of lattice parameter with the increasing presence of nitrogen vacancies up to ca. 80% was observed.\n Klíčová slova: titanium nitride; TiNx; ab initio simulation; density functional theory; DFT; vacancies; lattice parameter; surface energy Dokument je dostupný na externích webových stránkách.
Ab-initio study of surface energies and structural influece of vacancies in titanium nitride nanolayer

The surface energies of 8 crystallographic planes and effects of nitrogen vacancies on the lattice parameter in rock salt-like structure of TiN (σ-TiN) were studied using ab-initio method of density ...

Lebeda, M.; Vlčák, P.; Veřtát, P.; Drahokoupil, Jan
Fyzikální ústav, 2021

Emergence of dark ZnO nanorods by hydrogen plasma treatment
Remeš, Zdeněk; Buryi, Maksym; Sharma, Dhananjay Kumar; Artemenko, Anna; Mičová, J.; Rezek, B.; Poruba, A.; Hsu, H.S.; Potocký, Štěpán; Babin, Vladimir
2021 - anglický
We employed a custom-built inductively coupled plasma (ICP) 13.56 MHz reactor with up to 300 W RF discharge power. Hydrothermally grown ZnO nanorods were exposed to the ICP plasma with a mixture of hydrogen and argon for up to 30 min, followed in-situ by plasma oxidation. Plasma properties were monitored by optical emission spectroscopy (OES) and by measuring the self-bias potential of the stainless steel sample holder separated from the ground by a blocking capacitor. The exciton-related UV photoluminescence of ZnO nanorods and optical absorption increases significantly after the plasma treatment. We attribute it to the complex changes of ZnO surface electronic states that also give rise to its black color visually. Klíčová slova: ZnO; ICP; photoluminescence Dokument je dostupný na externích webových stránkách.
Emergence of dark ZnO nanorods by hydrogen plasma treatment

We employed a custom-built inductively coupled plasma (ICP) 13.56 MHz reactor with up to 300 W RF discharge power. Hydrothermally grown ZnO nanorods were exposed to the ICP plasma with a mixture of ...

Remeš, Zdeněk; Buryi, Maksym; Sharma, Dhananjay Kumar; Artemenko, Anna; Mičová, J.; Rezek, B.; Poruba, A.; Hsu, H.S.; Potocký, Štěpán; Babin, Vladimir
Fyzikální ústav, 2021

Transformation of ZnO-based structures under heavy Mo doping: Defect states and luminescence
Buryi, Maksym; Remeš, Zdeněk; Děcká, Kateřina; Mičová, J.; Landová, Lucie
2021 - anglický
Hydrothermally grown ZnO-based structures were heavily doped with Mo (various doping levels from 2 to 25%). It has been found that Mo strongly affects the ZnO structure and morphology rather resulting in the complex, mixed zinc and molybdenum oxides creation. Moreover, the material phases transformation upon the increased Mo content was observed. ZnO material phase was observed only at low Mo doping level (2 and 5%). This correlated very well to the changes in the luminescence and electron paramagnetic resonance signals. Klíčová slova: ZnO; Mo doping; material phase transformation; luminescence; electron paramagnetic resonance Dokument je dostupný na externích webových stránkách.
Transformation of ZnO-based structures under heavy Mo doping: Defect states and luminescence

Hydrothermally grown ZnO-based structures were heavily doped with Mo (various doping levels from 2 to 25%). It has been found that Mo strongly affects the ZnO structure and morphology rather resulting ...

Buryi, Maksym; Remeš, Zdeněk; Děcká, Kateřina; Mičová, J.; Landová, Lucie
Fyzikální ústav, 2021

TCO work function tuning by nanodiamonds
Čermák, Jan; Miliaieva, Daria; Sokeng-Djoumessi, A.; Hoppe, H.; Stehlík, Štěpán
2021 - anglický
Deposition of nanodiamonds is found to be able to adjust the work function of transparent conductive oxides that are commonly used in photovoltaics. It also turned out that the change is dependent on the nanodiamond surface termination and that it is not stable in time. Klíčová slova: nanodiamonds; Kelvin probe force microscopy; work function; stability Dokument je dostupný na externích webových stránkách.
TCO work function tuning by nanodiamonds

Deposition of nanodiamonds is found to be able to adjust the work function of transparent conductive oxides that are commonly used in photovoltaics. It also turned out that the change is dependent on ...

Čermák, Jan; Miliaieva, Daria; Sokeng-Djoumessi, A.; Hoppe, H.; Stehlík, Štěpán
Fyzikální ústav, 2021

Polyvinylpyrrolidone coating for nanodiamond stabilization in saline solution and silver nanoparticle decoration
Kolářová, Kateřina; Miliaieva, Daria; Stehlík, Štěpán
2021 - anglický
This work presents use of polyvinylpyrrolidone (PVP) for multipurpose coating of oxidized high-pressure high-temperature and detonation nanodiamonds. This simple way of nanodiamonds surface modification aims to improve their colloidal stability in biological environments and reduce their proneness to agglomeration. PVP immobilized on nanodiamond surface also provides for nanodiamond-supported AgNPs preparation by in situ synthesis using AgNO3 as a metallic nanoparticles precursor. Dynamic light scattering (DLS) and UV-vis spectroscopy were used for evaluation of nanoparticles size distribution and dispersibility in water and after exposition of nanoparticles in saline solution. Images acquired by scanning electron microscopy and transmission electron microscope validate the possibility of binding ~ 10 nm AgNPs to nanodiamonds surface. Klíčová slova: nanodiamonds; silver nanoparticles; colloid solution Dokument je dostupný na externích webových stránkách.
Polyvinylpyrrolidone coating for nanodiamond stabilization in saline solution and silver nanoparticle decoration

This work presents use of polyvinylpyrrolidone (PVP) for multipurpose coating of oxidized high-pressure high-temperature and detonation nanodiamonds. This simple way of nanodiamonds surface ...

Kolářová, Kateřina; Miliaieva, Daria; Stehlík, Štěpán
Fyzikální ústav, 2021

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