Number of found documents: 987
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INFLUENCE OF GRAPHITE UPON THE KINETICS OF HYDROGEN SORPTION IN Mg@Mg17Al12
Čermák, Jiří; Král, Lubomír; Roupcová, Pavla
2018 - English
Influence of graphite addition to the ball-milling charge composed of Mg splinters and Mg17Al12 particles upon the hydrogen sorption was investigated at sorption temperature 623 K. Measurements were carried out by Sieverts method. Graphite facilitates the ball-milling: It prevents re-agglomeration of crushed particles into large secondary particles. It also suppresses sticking the milled material to the balls and walls of the milling jar. It was found that an increase of carbon concentration up to a certain limit c(L) lying between 14 and 23 wt. % C, carbon increases both the absorption and the desorption rates and hydrogen storage capacity. Above c(L), carbon causes a considerable decrease in HS capacity, which spoils the application potential of Mg@Mg17Al12/C. Crystallite size of the material under study, obtained by XRD, is in the order of tens of nm. Keywords: storage; Hydrogen storage; Mg alloys; graphite Available at various institutes of the ASCR
INFLUENCE OF GRAPHITE UPON THE KINETICS OF HYDROGEN SORPTION IN Mg@Mg17Al12

Influence of graphite addition to the ball-milling charge composed of Mg splinters and Mg17Al12 particles upon the hydrogen sorption was investigated at sorption temperature 623 K. Measurements were ...

Čermák, Jiří; Král, Lubomír; Roupcová, Pavla
Ústav fyziky materiálů, 2018

Study of mechanical properties of nanolayered Ti/Ni coatings
Zábranský, L.; Václavík, R.; Přibyl, R.; Ženíšek, J.; Souček, P.; Buršík, Jiří; Fořt, Tomáš; Buršíková, V.
2018 - English
The aim of the present work was to study the dependence of mechanical properties of Ti/Ni multilayer thin films on the thicknesses of constituent Ti and Ni layers. The multilayer thin films were synthesized by deposition of Ti and Ni layers alternately on single crystalline silicon substrates using direct current magnetron sputtering method. Thicknesses of Ti and Ni layers varied from 1.7 nm to 100 nm. The micro-structure of the multilayer films was studied using X-ray diffraction technique, scanning electron microscopy with focused ion beam technique and transmission electron microscopy. Mechanical properties obtained from nanoindentation experiments were discussed in relation to microstructural observations. Keywords: Ti/Ni; multilayers; magnetron sputtering; nanoindentation; TEM Available at various institutes of the ASCR
Study of mechanical properties of nanolayered Ti/Ni coatings

The aim of the present work was to study the dependence of mechanical properties of Ti/Ni multilayer thin films on the thicknesses of constituent Ti and Ni layers. The multilayer thin films were ...

Zábranský, L.; Václavík, R.; Přibyl, R.; Ženíšek, J.; Souček, P.; Buršík, Jiří; Fořt, Tomáš; Buršíková, V.
Ústav fyziky materiálů, 2018

HIGH - TEMPERATURE CREEP BEHAVIOUR OF CAST COBALT-BASE SUPERALLOYS
Dvořák, Jiří; Král, Petr; Kvapilová, Marie; Hrbáček, Karel; Sklenička, Václav
2018 - English
Two cast and heat-treated NbC and TaC – strengthened cobalt superalloys have been developed for a precision casting of spinner discs for glass wool industry. In this work constant load creep tests in tension were carried out in argon atmosphere at three testing temperature 900, 950 and 1000 °C and at the initial applied stresses ranged from 40 to 200 MPa. All the tests were continued until the final fracture. The results of creep testing were combined with microstructural and fractographic examinations by means of light and scanning electron microscopy. A mutual comparison of creep characteristics of the investigated superalloys under comparable creep loading conditions showed that NbC-strengthened superalloy exhibited longer creep life than TaC-strengthened one. Further, it was found that carbide precipitation is the primary strengthening mechanism in both cobalt-base superalloys under investigation and the amount, morphology\nand type of carbides have the decisive effect on the creep properties including creep damage and fracture processes. By contrast, NbC-superalloy exhibited a more brittle character of creep fracture mode than TaCstrengthened superalloy. This study was initiated to investigate in more details creep deformation processes and the effect of the creep microstructure and damage evolution on both investigated superalloys. The different behaviour and properties of studied superalloys were explained based on the received results of this study. Keywords: Co-based superalloys; creep tests; microstructure evolution; carbide precipitation; damage process Available at various institutes of the ASCR
HIGH - TEMPERATURE CREEP BEHAVIOUR OF CAST COBALT-BASE SUPERALLOYS

Two cast and heat-treated NbC and TaC – strengthened cobalt superalloys have been developed for a precision casting of spinner discs for glass wool industry. In this work constant load creep tests in ...

Dvořák, Jiří; Král, Petr; Kvapilová, Marie; Hrbáček, Karel; Sklenička, Václav
Ústav fyziky materiálů, 2018

PILOT ANALYSIS OF CHEVRON NOTCH LIGAMENT AREA FOR APPLICATION\nON QUASI-BRITTLE MATERIALS
Seitl, Stanislav; Růžička, P.; Miarka, P.; Sobek, J.
2018 - English
Specimens for the bending tests with the chevron notch are standardized for the\nevaluation of the fracture toughness of various materials. The main advantage of this test\nset-up is that no sharp pre-crack has to be introduced, because a sharp crack is formed\nduring loading at the beginning of the test. Furthermore, no crack length measurement is\nrequired, and a stable crack growth can be reached due to geometry of the notch. In this\ncontribution a difference of the ligament area of the specimens with the straight through\nnotch and the chevron notch was investigated Keywords: Fracture mechanics; chevron notch; ligament area; work of fracture; straight notch; blunt Available at various institutes of the ASCR
PILOT ANALYSIS OF CHEVRON NOTCH LIGAMENT AREA FOR APPLICATION\nON QUASI-BRITTLE MATERIALS

Specimens for the bending tests with the chevron notch are standardized for the\nevaluation of the fracture toughness of various materials. The main advantage of this test\nset-up is that no sharp ...

Seitl, Stanislav; Růžička, P.; Miarka, P.; Sobek, J.
Ústav fyziky materiálů, 2018

HYDROGEN SORPTION BEHAVIOR OF CHOSEN BINARY MAGNESIUM-CONTAINING INTERMETALLICS
Čermák, Jiří; Král, Lubomír; Roupcová, Pavla
2018 - English
Hydrogen absorption in chosen binary Mg-X (X-Al, Ga, In, Si and Sn) intermetallics was studied. These compounds are prospective as additives in other Mg-based hydrogen storage materials. From this point of view it is desirable to know the hydrogen solubility in Mg-X and their resistivity against hydride formation. The present study was carried out at temperatures up to 623 K. Keywords: Hydrogen storage; magnesium alloys; Mg-based intermetallics Available at various institutes of the ASCR
HYDROGEN SORPTION BEHAVIOR OF CHOSEN BINARY MAGNESIUM-CONTAINING INTERMETALLICS

Hydrogen absorption in chosen binary Mg-X (X-Al, Ga, In, Si and Sn) intermetallics was studied. These compounds are prospective as additives in other Mg-based hydrogen storage materials. From this ...

Čermák, Jiří; Král, Lubomír; Roupcová, Pavla
Ústav fyziky materiálů, 2018

Quantum-mechanical study of magnetic properties of superalloy nanocomposite phase Fe2AlTi
Slávik, Anton; Miháliková, Ivana; Friák, Martin; Všianská, Monika; Šob, Mojmír
2018 - English
The L21-structure Fe2AlTi intermetallic compound is one of the two phases identified in Fe-Al-Ti superalloy nanocomposites. Experimental data related to low-temperature magnetic properties of this Heusler compound indicate that magnetic moment is about 0.1 Bohr magneton per formula unit. In contrast, previous quantum-mechanical calculations predicted Fe2AlTi to have much higher magnetic moment, 0.9 Bohr magneton per formula unit. In order to solve this discrepancy between the theory and experiment we have performed a series of quantum-mechanical fix-spin-moment calculations and compared our results with those for non-magnetic state. It turns out that the total energy of the non-magnetic state is only by 10.73 meV/atom higher than that of the magnetic state. When applying Boltzmann statistics to this very small energy difference we predict that the non-magnetic state appears at non-zero temperatures with significant probabilities (for instance, 22.36 % at T = 100 K) and reduces the overall magnetic moment. As another mechanism lowering the magnetization we studied selected shape deformations, in particular trigonal shearing. Fe2AlTi exhibits a compression-tension asymmetry with respect to these strains and, for example, the strain 0.08 destabilizes the spin-polarized state, leaving the non-magnetic state as the only stable one. Keywords: Ab initio calculations; Fe-Al based superalloys; Fixed-spin-moment; Nanocomposites Available at various institutes of the ASCR
Quantum-mechanical study of magnetic properties of superalloy nanocomposite phase Fe2AlTi

The L21-structure Fe2AlTi intermetallic compound is one of the two phases identified in Fe-Al-Ti superalloy nanocomposites. Experimental data related to low-temperature magnetic properties of this ...

Slávik, Anton; Miháliková, Ivana; Friák, Martin; Všianská, Monika; Šob, Mojmír
Ústav fyziky materiálů, 2018

ESTIMATION OF EQUILIBRIUM HYDROGEN PRESSURE - A NEW METHOD
Čermák, Jiří; Král, Lubomír
2018 - English
A new method is proposed to estimation of hydrogen pressure in equilibrium with hydride phase in a hydrogen\nstorage material. It is applicable both for hydrogen absorption and desorption in cases where the hydride phase\nis formed by nucleation and growth mechanism. The proposed method saves considerably the experimental\ntime replacing the conventional time consuming measurement of pressure-composition isotherms, the so\ncalled PCT curves. The proposed evaluation procedure is illustrated using hydrogen chemi-sorption at\ntemperatures 623 K, 573 K and 523 K in chosen hydrogen storage alloys Mg-Si-C, Mg-Li-C and Mg-Na-C. Keywords: Hydrogen storage; magnesium; new method Available at various institutes of the ASCR
ESTIMATION OF EQUILIBRIUM HYDROGEN PRESSURE - A NEW METHOD

A new method is proposed to estimation of hydrogen pressure in equilibrium with hydride phase in a hydrogen\nstorage material. It is applicable both for hydrogen absorption and desorption in cases ...

Čermák, Jiří; Král, Lubomír
Ústav fyziky materiálů, 2018

MICROSTRUCTURE AND COMPOSITION OF FINE PARTICLES RELEASED BY CAR BRAKING
Švábenská, Eva; Roupcová, Pavla; Pizúrová, Naděžda; Schneeweiss, Oldřich
2018 - English
Vehicular traffic is connected with large volume of fine particles released during brake processes of cars. Our research is focused on the phase, structure and chemical analysis of the fine particles taken from some car brake parts by their services. The information on structure and phase composition was obtained by X-Ray Powder Diffraction, Mossbauer Spectroscopy, scanning electron microscopy with EDX and transmission electron microscopy. The results of the wear debris analysis are compared with original brake materials components. Most of recognized particles are based mainly on iron oxides. Wear brake particles are discussed in the relation to the potential risk to the environment and human health. Keywords: wear; Nanoparticles; wear debris; environment Available at various institutes of the ASCR
MICROSTRUCTURE AND COMPOSITION OF FINE PARTICLES RELEASED BY CAR BRAKING

Vehicular traffic is connected with large volume of fine particles released during brake processes of cars. Our research is focused on the phase, structure and chemical analysis of the fine particles ...

Švábenská, Eva; Roupcová, Pavla; Pizúrová, Naděžda; Schneeweiss, Oldřich
Ústav fyziky materiálů, 2018

HYDROGEN STORAGE PROPERTIES OF GRAPHENE OXIDE MATERIALS PREPARED BY DIFFERENT WAYS
Král, Lubomír; Čermák, Jiří; Bytesnikova, Z.
2018 - English
Graphene-based materials show unique properties. These single layered materials consist of 2D structure of carbon atoms, belong to the strongest known materials, that are very mechanically flexible, optically transparent and that are excellent electrical and thermal conductors. Recently, several studies on these types of materials have highlighted the potential of this material for hydrogen storage (HS) and raised new hopes for the development of an effective solid-state HS media. In the present paper, the structure and HS properties of graphene oxide (GO) and chemically reduced graphene oxide (rGO) produced by different procedures were studied. Hydrogen sorption characteristics of GO and rGO were measured using the Sieverts-type gas sorption analyzer PCT-Pro Setaram Instrumentation. The study of HS was carried out at temperature range from 198 K to 423 K under hydrogen pressure from 1x10(-4) to 4 MPa. Keywords: adsorption; reduction; graphite; Graphene oxide; hydrogen storage; adsorption; desorption Available at various institutes of the ASCR
HYDROGEN STORAGE PROPERTIES OF GRAPHENE OXIDE MATERIALS PREPARED BY DIFFERENT WAYS

Graphene-based materials show unique properties. These single layered materials consist of 2D structure of carbon atoms, belong to the strongest known materials, that are very mechanically flexible, ...

Král, Lubomír; Čermák, Jiří; Bytesnikova, Z.
Ústav fyziky materiálů, 2018

DISPLACEMENT FIELD ANALYSIS IN WEDGE SPLITTING TEST\nSPECIMEN BY ODM METHOD
Seitl, S.; Miarka, P.; Růžička, V.; Malíková, Lucie; Merta, I.
2018 - English
Multi-parameter fracture mechanics is nowadays quite extensively applied when cracked\nstructures/specimens are investigated. The reason is that it has been shown that it can be\nhelpful and bring more accurate results when fracture processes happen in a larger\nregion around the crack tip, what can be typical for material like concrete or other\nmaterials with quasi-brittle behaviour. Various relative crack length configurations have\nbeen chosen in order to investigate the importance of the higher-order terms of the\nWilliams power expansion on the crack-tip stress field distribution in Wedge splitting\ntest specimen. The higher-order terms are calculated by means of the over-deterministic\nmethod from displacements of nodes around the crack tip obtained by a finite element\nanalysis in different radial distances from the crack tip. The effect of the constraint level\nis investigated. Although the third and higher terms of the Williams series are very often\nneglected, their influence on the opening stress values is investigated. Keywords: ODM, WST; WST; constraint; Williams series; FEM; stress intensity factor; displacement Available at various institutes of the ASCR
DISPLACEMENT FIELD ANALYSIS IN WEDGE SPLITTING TEST\nSPECIMEN BY ODM METHOD

Multi-parameter fracture mechanics is nowadays quite extensively applied when cracked\nstructures/specimens are investigated. The reason is that it has been shown that it can be\nhelpful and bring ...

Seitl, S.; Miarka, P.; Růžička, V.; Malíková, Lucie; Merta, I.
Ústav fyziky materiálů, 2018

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