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Number of found documents: 37245

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Application of In situ TR Spectroelectrochemical Techniques in Determination of Redox Mechanism of Bioactive Compounds
Sokolová, Romana; Jiroušková, Eliška; Degano, I.; Wantulok, J.; Nycz, J.
2023 - English The electron transfer reactions play an important role in many natural processes. Reactions such as \ndissociation, protonation, and reactions with water and other small molecules often occur in \nbiotransformation. The reaction schemes involving these chemical reactions coupled to the \nelectron transfer can be determined by cyclic voltammetry. Additionally, in \nsitu spectroelectrochemistry can efficiently contribute to the determination of oxidation or \nreduction mechanism. This technique provides information about the electroactive chromophore during \nthe redox process allowing to identification the first reaction intermediates. The final reaction \nproducts were identified by chromatographic techniques. This study represents a key role of TR \nspectroelectrochemistry in the determination of reaction intermediates in the case of \n1,10- phenanthroline derivative substituted by bioactive phenothiazine unit and \ndrug 3- fluorophenmetrazine (2-(3-fluorophenyl)-3-methylmorpholine, 3-FPM). Co pound 3-FPM\nhave recently appeared as the new psychoactive substance in the drug market.\n Keywords: IR spectroelectrochemistry; psychoactive substances; oxidation mechanism Available on request at various institutes of the ASCR Application of In situ TR Spectroelectrochemical Techniques in Determination of Redox Mechanism of Bioactive Compounds

The electron transfer reactions play an important role in many natural processes. Reactions such as \ndissociation, protonation, and reactions with water and other small molecules often occur in ...

Sokolová, Romana; Jiroušková, Eliška; Degano, I.; Wantulok, J.; Nycz, J.
Ústav fyzikální chemie J. Heyrovského, 2023

A polarizable reference electrode
Mareček, Vladimír
2023 - English New concept of a reference electrode for electrochemical systems resolves a problem of a poor \npotential stability of refence electrodes based on the distribution of a strongly \nhydrophobic common cation between two immiscible electrolyte solutions (TTTES). The use of a \npolarizable metal electrode instead of a classical reference electrode is demonstrated in \n a modified conventional four-electrode cell with TTTES. A simple battery operated potentiostat \ncontrols the working electrode potential in a three-electrode configuration. The working metal \nelectrode then serves as a polarizable reference organic solvent electrode in a four-electrode \nsystem for the polarization of the water/organic solvent interface.\n\n Keywords: reference electrode; liquid/liquid interface; chloride extraction Available on request at various institutes of the ASCR A polarizable reference electrode

New concept of a reference electrode for electrochemical systems resolves a problem of a poor \npotential stability of refence electrodes based on the distribution of a strongly ...

Mareček, Vladimír
Ústav fyzikální chemie J. Heyrovského, 2023

Zikmunda Hrubého z Jelení etymologický pokus
Vykypěl, Bohumil
2023 - Czech Keywords: etymology; Zikmund Hrubý Available at various institutes of the ASCR Zikmunda Hrubého z Jelení etymologický pokus

Vykypěl, Bohumil
Ústav pro jazyk český, 2023

On the structure and values of betweenness centrality in dense betweenness-uniform graphs
Ghanbari, B.; Hartman, David; Jelínek, V.; Pokorná, Aneta; Šámal, R.; Valtr, P.
2023 - English Betweenness centrality is a network centrality measure based on the amount ofshortest paths passing through a given vertex. A graph is betweenness-uniform (BUG)if all vertices have an equal value of betweenness centrality. In this contribution, wefocus on betweenness-uniform graphs with betweenness centrality below one. Wedisprove a conjecture about the existence of a BUG with betweenness valueαforany rational numberαfrom the interval (3/4,∞) by showing that only very few be-tweenness centrality values below 6/7 are attained for at least one BUG. Furthermore,among graphs with diameter at least three, there are no betweenness-uniform graphswith a betweenness centrality smaller than one. In graphs of smaller diameter, thesame can be shown under a uniformity condition on the components of the comple-ment. Available in digital repository of the ASCR On the structure and values of betweenness centrality in dense betweenness-uniform graphs

Betweenness centrality is a network centrality measure based on the amount ofshortest paths passing through a given vertex. A graph is betweenness-uniform (BUG)if all vertices have an equal value of ...

Ghanbari, B.; Hartman, David; Jelínek, V.; Pokorná, Aneta; Šámal, R.; Valtr, P.
Ústav informatiky, 2023