No (209)
Used filters
(4)
Number of found documents:
209
Published from
to
Novel nanocomposite materials for power engineering
Boček, J.; Matějka, Libor; Mentlík, V.
2010 - English
The epoxy-POSS nanocomposites were prepared and their electrical/dielectric and thermomechanical properties were determined. The mono- and octa-epoxyfunctionalized POSS (POSS,E1 and POSS,E8) were covalently incorporated in the epoxy network matrix DGEBA- 3,3’-dimethyl-4,4’-diaminocyclohexylmethane (Laromin C260) as pendant units or as polyhedral junctions, respectively. While the POSS junctions are well dispersed in the hybrid network DGEBA-Laromin-POSS,E8, the pendant POSS aggregate to form large crystalline POSS domains.
Keywords:
nanocomposite; epoxy resin; insulating system
Available at various institutes of the ASCR
Novel nanocomposite materials for power engineering
The epoxy-POSS nanocomposites were prepared and their electrical/dielectric and thermomechanical properties were determined. The mono- and octa-epoxyfunctionalized POSS (POSS,E1 and POSS,E8) were ...
Cation and anion exchangers from nanofibrous polystyrene for fast water treatment
Marek, J.; Beneš, Milan J.; Jelínek, L.
2009 - English
Strongly acidic sulfonovaný cation exchanger on polystyrene nanofibrous matrix (Nanospider TM technology) was prepared by simultaneous sulfonation and crosslinking. Weakly basic nanofibrous anion exchanger was prepared after transformation of sulfogroups to sulfochloride by reaction with ethylene diamine. Nanofibrous products were characterized by sorption capacity. They have sorption kinetic significantly faster in comparison with standard granular ion exchangers. Současnou sulfonací a síťováním byl připraven silně kyselý sulfonový katex na polystyrenové nanovláknité matrici (Nanospider TM technologie). Slabě bázický anex byl připraven po převedení sulfoskupin na sulfochlorid reakci s ethylen diaminem. Nanovláknité produkty byly charakterizovány pomocí sorpční kapacity. Mají kinetiku sorpce výrazně rychlejší než standardní sorbenty granulární.
Keywords:
polystyrene; nanofiber; ion exchanger
Available at various institutes of the ASCR
Cation and anion exchangers from nanofibrous polystyrene for fast water treatment
Strongly acidic sulfonovaný cation exchanger on polystyrene nanofibrous matrix (Nanospider TM technology) was prepared by simultaneous sulfonation and crosslinking. Weakly basic nanofibrous anion ...
Self-assembled nanostructures in copolymer blends: SAXS, SANS and TEM study
Holoubek, Jaroslav; Baldrian, Josef; Hromádková, Jiřina; Steinhart, Miloš
2009 - English
Phenomena associated with the phase behaviour and self-assembled nanostructures of three block copolymer systems have been studied by small-angle X-ray scattering (SAXS), small-angle neutron scattering (SANS) and transmision electron microscopy (TEM)
Keywords:
total hip replacement; polyethylene wear; aseptic loosening
Available at various institutes of the ASCR
Self-assembled nanostructures in copolymer blends: SAXS, SANS and TEM study
Phenomena associated with the phase behaviour and self-assembled nanostructures of three block copolymer systems have been studied by small-angle X-ray scattering (SAXS), small-angle neutron ...
Surface properties of polyethylene grafted by plasma
Novák, I.; Nedelčev, T.; Krupa, I.; Števiar, M.; Chodák, I.; Mosnáček, J.; Špírková, Milena; Chehimi, M. M.
2008 - English
The aim of the paper is an investigation of surface properties of the polyethylene modified by radio-frequency discharge plasma as well as of the polymer modified by plasma and subsequently grafted with alkoxyvinylsilanes. Cílem tohoto příspěvku je studium povrchových vlastností polyethylenu modifikovaného radiofrekvenčním plasmovým výbojem a plasmou modifikovaného polymeru s naroubovanými alkoxyvinylsilany.
Keywords:
polyethylene; surface properties
Available at various institutes of the ASCR
Surface properties of polyethylene grafted by plasma
The aim of the paper is an investigation of surface properties of the polyethylene modified by radio-frequency discharge plasma as well as of the polymer modified by plasma and subsequently grafted ...
Metal organophosphonates and their intercalation compounds as inorganic-organic hydrid materials and nanomaterials
Zima, Vítězslav; Svoboda, Jan; Melánová, Klára; Beneš, L.
2008 - English
We prepared several new phenylphosphonates and 4-carboxyphenylphosphonates of alkaline earth metals and copper and characterized them by powder X-ray diffraction, thermogravimetric analysis, energy-dispersive X-ray analysis, elemental analysis and infrared spectroscopy. For four of these compounds, their structure was determined from their powder X-ray diffraction patterns using an ab initio FOX program. The prepared alkaline-earth phenylphosphonates with general formula MeC6H5PO3yH2O (Me = Ca, Sr, Ba) were found to be suitable hosts for intercalation reactions. Připravili jsme několik nových fenylfosfonátů a 4-karboxyfenylfosfonátů kovů alkalických zemin a mědi a charakterizovali je pomocí práškové rentgenové difrakce, termogravimetrické analýzy, EDX, elem. analýzy a infračervené spektroskopie. Byla určena struktura čtyřech těchto sloučenin pomocí ab initio programu FOX z práškových rtg. dat. Připravené fenylfosfonáty alkalických kovů se ukázaly být vhodnými hostitelskými materiály pro interkalační reakce.
Keywords:
intercalation
Available at various institutes of the ASCR
Metal organophosphonates and their intercalation compounds as inorganic-organic hydrid materials and nanomaterials
We prepared several new phenylphosphonates and 4-carboxyphenylphosphonates of alkaline earth metals and copper and characterized them by powder X-ray diffraction, thermogravimetric analysis, ...
Synthesis of titanate nanotubes: influence of TiO2 modification on crystalline structure and morphology
Králová, Daniela; Šlouf, Miroslav; Kužel, R.
2008 - English
This work is focused on preparation of titanate nanotubes (Ti-NT) from various crystalline modifications of TiO2. Different source micro/nanopowders of TiO2 yielded Ti-NT with similar sizes, shapes and structures. Residual TiO2 particles in final Ti-NT suspensions were eliminated by modification of preparation procedure. Morphology and crystalline structure of both source TiO2 and final Ti-NT were investigated by means of electron microscopy, electron diffraction and X-ray diffraction. Předmětem studia byla syntéza titanátových nanotrubiček (Ti-NT) z různých krystalických modifikací TiO2. Při syntéze se vycházelo ze čtyř různých druhů TiO2 mikro- a nanoprášků. Úpravou postupu syntézy se podařilo zcela odstranit zbytkový TiO2 ve výsledném produktu. Morfologie a krystalická struktura zdrojových TiO2 prášků a finálních Ti-NT byla charakterizována pomocí elektronové mikroskopie, elektronové difrakce a difrakce rentgenova záření.
Keywords:
titanate nanotubes
Available at various institutes of the ASCR
Synthesis of titanate nanotubes: influence of TiO2 modification on crystalline structure and morphology
This work is focused on preparation of titanate nanotubes (Ti-NT) from various crystalline modifications of TiO2. Different source micro/nanopowders of TiO2 yielded Ti-NT with similar sizes, shapes ...
Recent Results of the Study of Phase Change Memory Materials
Frumar, M.; Wágner, T.; Přikryl, J.; Hromádko, L.; Frumarová, Božena; Němec, P.
2008 - English
Recent results of the study of phase change materials, of their structure, composition, properties and models fast crystallization and amorphization are discussed. Nedávné výsledky studia materiálů pro pamětí s fázovými změnami, jejich struktura, složení, vlastnosti a modely jejich rychlé krystalizace a amorfizace jsou diskutovány.
Keywords:
phase change memory
Available at various institutes of the ASCR
Recent Results of the Study of Phase Change Memory Materials
Recent results of the study of phase change materials, of their structure, composition, properties and models fast crystallization and amorphization are discussed....
Diffraction measurements at sources of synchrotron radiation
Hašek, Jindřich
2008 - English
The paper summarizes the present state of art in the use of different sources of synchrotron radiation in protein structure determination and discusses possibility of the future development. Current experiences with the newly developed "small intensive sources of radiation" MIRROCLE and LYNCEAN indicate that the practical usage of these sources needs really long and difficult development. The three XFEL instruments presently under construction in Japan, USA and Germany will open new areas for science. They are complementary to current synchrotron equipment used for protein crystallography but cannot substitute it and the current sources of synchrotron radiation of the third generation equipped by undulators will remain dominant at least in the next decade. Článek dává přehled současného stavu využití různých zdrojů synchrotronového záření při zobrazování struktury biologických makromolekul a diskutuje další možný vývoj v proteinové krystalografii. Současné zkušenosti ukazují, že nově vyvíjené "malé zdroje intensivního záření " MIRROCLE and LYNCEAN potřebují pro praktické využití v biochemických laboratořích ještě dlouhý a obtížný vývoj. Tři XFEL zařízení budované v Japonsku, USA a Německu umožní rozvoj nových směrů ve vědě, které vhodně doplňují současnou struktuní analýzu proteinů prováděnou v současné době převážně na synchrotronech třetí generace. Vše nasvědčuje tomu, že zařízení vybavené moderními undulátory na synchrotronech třetí generace zůstanou plně dominantní metodou pro proteinovou krystalografii i v příštích desetiletích.
Keywords:
synchrotron radiation
Available at various institutes of the ASCR
Diffraction measurements at sources of synchrotron radiation
The paper summarizes the present state of art in the use of different sources of synchrotron radiation in protein structure determination and discusses possibility of the future development. Current ...
Study of biodegradable starch/polycaprolactone blends by solid-state NMR methods
Spěváček, Jiří; Brus, Jiří; Divers, T.; Grohens, Y.
2007 - English
1H relaxation times T1(H) and T1.rho.(H) were measured via 13C detection on starch/polycaprolactone (PCL) and starch formate/PCL blends to characterize their morphology (domain size). From the results it follows that while blends starch/PCL are phase-separated on the scale 20-110 nm, starch formate/PCL blend is homogeneously mixed on this scale. Therefore formylation of starch significantly improves its miscibility with PCL. Užitím 13C detekce byly měřeny relaxační doby T1(H) a T1.rho.(H) u směsí škrob/polykaprolakton (PKL) a formylovaný škrob/PKL k charakterizaci jejich morfologie (velikost domén). Z výsledků vyplynulo, že zatímco ve směsích škrob/PKL jsou ve škále 20-110 nm obe složky fázově separovány, ve směsi formylovaný škrob/PKL jsou v této škále obě složky homogenně promíseny. Formylace škrobu tedy podstatně zlepšuje jeho mísitelnost s PKL.
Keywords:
biodegradable polymers; starch/polycaprolactone blends; morphology
Available at various institutes of the ASCR
Study of biodegradable starch/polycaprolactone blends by solid-state NMR methods
1H relaxation times T1(H) and T1.rho.(H) were measured via 13C detection on starch/polycaprolactone (PCL) and starch formate/PCL blends to characterize their morphology (domain size). From the results ...
Effects of mixed compatibilizers on morphology and rheological properties of polystyrene/polyolefin blends
Mikešová, Jana; Starý, Zdeněk; Fortelný, Ivan
2007 - English
The influence of a new compatibilization system (mixtures of styrene-butadiene triblock copolymer (SBS) with ethene-propene random copolymer (EPM)) on flow properties and morphology of polystyrene/low-density polyethylene and polystyrene/polypropylene bleds was studied. Byly studovány změny struktury a tokových vlastností nemísitelných směsí polystyren/polyolefiny vyvolané použitím nových směsných kompatibilizátorů. Navržený kompatibilizační systém je tvořen různými poměry styren-butadien-styrenového blokového kopolymeru (SBS) a ethylen-propylenového statistického kopolymeru (EPM).
Keywords:
melt rheology; immiscible polymer blends; compatibilization
Available at various institutes of the ASCR
Effects of mixed compatibilizers on morphology and rheological properties of polystyrene/polyolefin blends
The influence of a new compatibilization system (mixtures of styrene-butadiene triblock copolymer (SBS) with ethene-propene random copolymer (EPM)) on flow properties and morphology of ...
NRGL provides central access to information on grey literature produced in the Czech Republic in the fields of science, research and education. You can find more information about grey literature and NRGL at service web
Send your suggestions and comments to nusl@techlib.cz
Provider
Other bases