Number of found documents: 196
Published from to

Deposition of dried colloidal suspension via nanoelectrospray
Jonas, Vladimír; Týčová, Anna; Přikryl, Jan; Kotzianová, A.; Velebný, V.; Foret, František
2020 - English
Electrospray is a relatively well-established tool for the deposition of nanoparticles. In this work, we use nanoelectrospray (nES) operating at flow rates down to tens of nanoliters per minute. As a result, the formed aerosol consists of very small droplets quickly drying during the flight towards a counter-electrode. Therefore, we obtained deposits of increased homogeneous distribution without an undesirable coffee-ring effect. Moreover, the character of the aerosol plume is only a few millimeters wide, so it allows good control over the deposit localization. Keywords: nanoparticles; nanoelectrospray; silver Fulltext is available at external website.
Deposition of dried colloidal suspension via nanoelectrospray

Electrospray is a relatively well-established tool for the deposition of nanoparticles. In this work, we use nanoelectrospray (nES) operating at flow rates down to tens of nanoliters per minute. As a ...

Jonas, Vladimír; Týčová, Anna; Přikryl, Jan; Kotzianová, A.; Velebný, V.; Foret, František
Ústav analytické chemie, 2020

Chemical vapor generation of cadmium for analytical atomic spectrometry
Sagapova, Linda; Kodríková, Barbora; Svoboda, Milan; Musil, Stanislav; Kratzer, Jan
2020 - English
Chemical vapor generation of cadmium volatile compounds was optimized, several reaction modifiers based on inorganic salts and complexes of CrIII+, CoII+, TiIII+, TiIV+ were tested. Their use resulted in 4-5 times enhancement in sensitivity, reflected also in corresponding increase of generation efficiency and better repeatability. Generation efficiency was determined from a comparison between sensitivities obtained with chemical vapor generation and conventional solution nebulization, both simultaneously coupled with inductively coupled plasma mass spectrometry. The identity of the generated cadmium compounds was identified. Keywords: cadmium; chemical vapor generation; atomic absorption spectrometry Available in digital repository of the ASCR
Chemical vapor generation of cadmium for analytical atomic spectrometry

Chemical vapor generation of cadmium volatile compounds was optimized, several reaction modifiers based on inorganic salts and complexes of CrIII+, CoII+, TiIII+, TiIV+ were tested. Their use resulted ...

Sagapova, Linda; Kodríková, Barbora; Svoboda, Milan; Musil, Stanislav; Kratzer, Jan
Ústav analytické chemie, 2020

Stanovení rychlých změn koncentrací těkavých organických sloučenin pomocí difúzního denuderu
Křůmal, Kamil; Mikuška, Pavel
2019 - Czech
Stanovení rychlých změn koncentrací těkavých organických sloučenin bylo provedeno využitím difúzního denuderu se stékajícím filmem kapaliny, který umožňuje odběr vzorků v časových intervalech již od 2 minut. Determination of fast changes in concentrations of volatile organic compounds was performed using wet effluent diffusion denuder, which allows collection of samples in 2-min intervals. Keywords: monoterpenes; BTEX; denuder Available in digital repository of the ASCR
Stanovení rychlých změn koncentrací těkavých organických sloučenin pomocí difúzního denuderu

Stanovení rychlých změn koncentrací těkavých organických sloučenin bylo provedeno využitím difúzního denuderu se stékajícím filmem kapaliny, který umožňuje odběr vzorků v časových intervalech již od 2 ...

Křůmal, Kamil; Mikuška, Pavel
Ústav analytické chemie, 2019

Organické sloučeniny a markery ze spalování uhlí v různých typech kotlů používaných pro vytápění domácností
Křůmal, Kamil; Mikuška, Pavel; Horák, J.; Hopan, F.
2019 - Czech
Organické sloučeniny (polycyklické aromatické uhlovodíky) a organické markery (hopany) používané pro identifikaci zdrojů aerosolů byly měřeny v emisích ze spalování černého a hnědého uhlí. Uhlí bylo spalováno v různých kotlích používaných pro vytápění domácností v České republice, tj. prohořívací, odhořívací a automatický kotel. Organic compounds (polycyclic aromatic hydrocarbons) and organic markers (hopanes) used for the identification of aerosol emission sources were measured in emissions from the combustion of hard and brown coal. Coal was combusted in different\nboilers used for residential heating in the Czech Republic, i.e., overfire boiler, boiler with down-draft combustion and automatic boiler. Keywords: household heating; coal combustion; hopanes Available in digital repository of the ASCR
Organické sloučeniny a markery ze spalování uhlí v různých typech kotlů používaných pro vytápění domácností

Organické sloučeniny (polycyklické aromatické uhlovodíky) a organické markery (hopany) používané pro identifikaci zdrojů aerosolů byly měřeny v emisích ze spalování černého a hnědého uhlí. Uhlí bylo ...

Křůmal, Kamil; Mikuška, Pavel; Horák, J.; Hopan, F.
Ústav analytické chemie, 2019

On-line simultaneous determination of ammonia/ammonium in ambient air
Čapka, Lukáš; Mikuška, Pavel
2019 - English
Presented paper describes methods for on-line determination of gaseous ammonia and particulate ammonium in ambient air. Keywords: ammonia; ammonium; CGU-ACTJU sampler Available in digital repository of the ASCR
On-line simultaneous determination of ammonia/ammonium in ambient air

Presented paper describes methods for on-line determination of gaseous ammonia and particulate ammonium in ambient air.

Čapka, Lukáš; Mikuška, Pavel
Ústav analytické chemie, 2019

LIBS assessment of spatial photon-upconversion nanoparticle distribution in model plants (R. sativus and L. minor)
Modlitbová, P.; Novotný, K.; Hlaváček, Antonín; Pořízka, P.; Kaiser, J.
2019 - English
In the present study, radish (Raphanus sativus L.) and common duckweed (Lemna minor L.) were treated with an aqueous dispersion of carboxylated silica-coated photon-upconversion nanoparticles containing rare-earth elements (Y, Yb, and Er). The total content of rare earths and their bioaccumulation factors were determined in the root, hypocotyl, and leaves of R. sativus after 72 hours, and in L. minor fronds after 168 hours. In R. sativus, translocation factors were determined as the ratio of rare earths content in hypocotyl versus roots and in leaves versus hypocotyl. The lengths of the root and hypocotyl in R. sativus, as well as the frond area in L. minor were monitored as toxicity end points. To distinguish rare-earth bioaccumulation patterns, two-dimensional maps of elemental distribution in the whole R. sativus plant and in L. minor fronds were obtained by using laser-induced breakdown spectroscopy with a lateral resolution of 100 μm. Obtained results revealed that the tested nanoparticles became adsorbed on L. minor fronds and R. sativus roots, and got transferred from roots through the hypocotyl into leaves in R. sativus. Our results show that bioaccumulation patterns and spatial distribution of rare earths in nanoparticle-treated plants differ from those of positive control (the mixture of YCl3, YbCl3, and ErCl3). Keywords: photonupconversion nanoparticles; luminescent nanomaterials; bioaccumulation Available in digital repository of the ASCR
LIBS assessment of spatial photon-upconversion nanoparticle distribution in model plants (R. sativus and L. minor)

In the present study, radish (Raphanus sativus L.) and common duckweed (Lemna minor L.) were treated with an aqueous dispersion of carboxylated silica-coated photon-upconversion nanoparticles ...

Modlitbová, P.; Novotný, K.; Hlaváček, Antonín; Pořízka, P.; Kaiser, J.
Ústav analytické chemie, 2019

Optimization of photochemical vapor generation of nickel with ICP-MS detection
Šoukal, Jakub; Musil, Stanislav
2019 - English
Photochemical vapor generation of Ni has been investigated in detail using ICP-MS as the detector. Keywords: photochemical vapor generation; nickel; ICP-MS Available in digital repository of the ASCR
Optimization of photochemical vapor generation of nickel with ICP-MS detection

Photochemical vapor generation of Ni has been investigated in detail using ICP-MS as the detector.

Šoukal, Jakub; Musil, Stanislav
Ústav analytické chemie, 2019

Polycyklické aromatické uhlovodíky v PM1 aerosolu na 6 lokalitách v České republice
Křůmal, Kamil; Mikuška, Pavel
2019 - Czech
PAHs byly měřeny v zimní sezóně ve městech Ostrava-Radvanice (průmyslová lokalita), Brno, Mladá Boleslav, Kladno-Švermov, Čelákovice, Košetice (pozaďová lokalita). Z koncentrací PAHs v PM1 aerosolu byly počítány rizika vzniku rakoviny plic. PAHs were measured in winter seasons in cities/towns Ostrava-Radvanice (industrial city), Brno, Mladá Boleslav, Kladno-Švermov, Čelákovice, Košetice (background town). Lifetime lung cancer risks of PAHs were calculated from concentrations of PAHs in PM1 aerosol. Keywords: PAHs; PM1; lung cancer risk Available in digital repository of the ASCR
Polycyklické aromatické uhlovodíky v PM1 aerosolu na 6 lokalitách v České republice

PAHs byly měřeny v zimní sezóně ve městech Ostrava-Radvanice (průmyslová lokalita), Brno, Mladá Boleslav, Kladno-Švermov, Čelákovice, Košetice (pozaďová lokalita). Z koncentrací PAHs v PM1 aerosolu ...

Křůmal, Kamil; Mikuška, Pavel
Ústav analytické chemie, 2019

Microfluidic device for cell counting and electrical lysis
Václavek, Tomáš; Křenková, Jana; Foret, František
2018 - English
This lecture presents two microfluidic devices as essential units for single cell proteomic analysis, firstly a device for cell counting based on resistive pulse sensing as an alternative to optical platforms based on visual control over the sample input, secondly a unit for electrical lysis of cells using direct current voltage pulses to lyse cells one by one with a possibility to analyze the distinct lysate zones by electrospray ionization mass spectrometry. Keywords: microfluidic devices; microextraction of basic drugs; single cell proteomic analysis; electrospray ionization mass spectrometry; cell lysis Fulltext is available at external website.
Microfluidic device for cell counting and electrical lysis

This lecture presents two microfluidic devices as essential units for single cell proteomic analysis, firstly a device for cell counting based on resistive pulse sensing as an alternative to optical ...

Václavek, Tomáš; Křenková, Jana; Foret, František
Ústav analytické chemie, 2018

Impact of post-harvest processing, geographical locality and production year on quality of selected medicinal plants
Burdějová, Lenka; Polovka, M.; Pořízka, J.
2018 - English
This study deals with the assessment of the impact of post-harvest treatment, geographical location and production years on 32 selected characteristics of medicinal plants grown in the Czech Republic. Dimethyl sulfoxide herbal extracts characteristics were evaluated by spectroscopic and chromatographic techniques. The results were processed by analysis of variance and multivariate statistical tools. Obtained results clearly proved the successful differentiation of herbal samples by means of canonical discrimination analysis according to post-harvest treatment (100%), geographical origin (82.9%) and production year (96.1%) confirming that studied factors may have significant effect on quality of medicinal plants. Keywords: HPLC-DAD; ICP-OES; plants extracts; herbal extracts Fulltext is available at external website.
Impact of post-harvest processing, geographical locality and production year on quality of selected medicinal plants

This study deals with the assessment of the impact of post-harvest treatment, geographical location and production years on 32 selected characteristics of medicinal plants grown in the Czech Republic. ...

Burdějová, Lenka; Polovka, M.; Pořízka, J.
Ústav analytické chemie, 2018

About project

NRGL provides central access to information on grey literature produced in the Czech Republic in the fields of science, research and education. You can find more information about grey literature and NRGL at service web

Send your suggestions and comments to nusl@techlib.cz

Provider

http://www.techlib.cz

Facebook

Other bases