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Development of Polymeric Enantioselective Membranes
Čížek, Jan
2024 - English
Enantiomers are molecules that share the same chemical formula but in space form mirror images of each other. Their reactions with other chiral molecules can be remarkably different, which is crucial mainly for pharmaceuticals and agrochemicals. However, industrialscale synthetic production of enantiomerically pure compounds is not always available. Therefore, the need for pure enantiomeric compounds drives the development and research on various separation methods. However, most methods used on the industrial scale are limited to specific compounds (diastereomeric recrystallization) or generally difficult and/or expensive to scale up (chromatography-related methods). Separation of enantiomers using membranes is promising\nthanks to the easy scalability and continuous operation of membrane processes. Various ideas about how the enantioselective membranes should look like have been published in the last thirty years. The mechanism of enantiomeric separation on a membrane is, however, highly specific, and still requires extensive research. In this work, four types of enantioselective polymeric membranes are presented.
Available in a digital repository NRGL
Development of Polymeric Enantioselective Membranes
Enantiomers are molecules that share the same chemical formula but in space form mirror images of each other. Their reactions with other chiral molecules can be remarkably different, which is crucial ...
Synthesis of Fluorinated Methyl β-Lactosides
Krčil, Aleš
2024 - English
In my contribution, I will describe the synthesis of a complete series of mono-deoxyfluorinated methyl β-lactosides (1–7). Their affinity towards hgals will be determined by analytical method ELISA. The synthesis relies on monosaccharide building blocks, which serves as key intermediates that are transformed into the target products through glycosylation followed by final deprotection steps.
Keywords:
flurinated carbohydrates; galectin; deoxyfluorination
Available in a digital repository NRGL
Synthesis of Fluorinated Methyl β-Lactosides
In my contribution, I will describe the synthesis of a complete series of mono-deoxyfluorinated methyl β-lactosides (1–7). Their affinity towards hgals will be determined by analytical method ELISA. ...
Investigation of Mechanical Processing of Solar Photovoltaic Panels
Šperlich, Antonín
2024 - English
This work aims to describe the possibilities of mechanical treatment of solar photovoltaic panels. In the first part, the shredding and milling process for the transformation of the product (whole panel) into material that can be further processed, was investigated. Milled material was sieved and analyzed. It was observed that this shredding also works as a selective grinding because three main products were produced. The second part of this work was aimed at the physical concentration of silver in real samples of milled solar photovoltaic panels by Knelson separator. This device (type of centrifugal separator) showed the ability to significantly increase the amount of silver in the outcome stream.
Keywords:
solar photovoltaic panels; selective milling; Knelson
Available in a digital repository NRGL
Investigation of Mechanical Processing of Solar Photovoltaic Panels
This work aims to describe the possibilities of mechanical treatment of solar photovoltaic panels. In the first part, the shredding and milling process for the transformation of the product (whole ...
Axial Dispersion and Mass Transfer in Bubble Column
Terentyak, Mark
2024 - English
The objective of the study is to experimentally investigate axial dispersion and mass transfer within a bubble column, examining their mutual interrelation\nand their correlation with operational parameters and AR1.
Keywords:
bubble column; axial dispersion; mass transfer
Available in a digital repository NRGL
Axial Dispersion and Mass Transfer in Bubble Column
The objective of the study is to experimentally investigate axial dispersion and mass transfer within a bubble column, examining their mutual interrelation\nand their correlation with operational ...
Exploring Bubble Dynamics with VOF Method Simulations: Insights from Two Fundamental Gas-Liquid Flow Case Studies
Harrandt, Václav
2024 - English
The present study focuses on the flow of Taylor bubbles, representing the interaction between the channel wall and the gas phase, and the collision of\na bubble with a vortex ring, serving as a model liquid-gas interaction. Understanding the former case can be essential to prevent the membrane\nfouling or the flow induced corrosion. The dynamics of the latter case is the predictive criterion for whether the initial mother bubble will break up into the daughter bubbles or not2 and this process can therefore be used as an idealized model of turbulent bubble flow.
Keywords:
bubble dynamics; multiphase interaction,; numerical simulation
Available in a digital repository NRGL
Exploring Bubble Dynamics with VOF Method Simulations: Insights from Two Fundamental Gas-Liquid Flow Case Studies
The present study focuses on the flow of Taylor bubbles, representing the interaction between the channel wall and the gas phase, and the collision of\na bubble with a vortex ring, serving as a model ...
The Influence of Geometric Parameters of 3D Printed Structured Beds on Hydrodynamic Characteristics of Trickle-Bed Reactor
Nyklíčková, Kateřina
2024 - English
The study examines a parametric set of POCS structures, where cubic cell is the basic element. The parameters such as strut diameter sd and cell size cs were varied1. These modifications are implemented with an emphasis on maintaining similar porosity and specific surface area for these structures.
Available in digital repository of the ASCR
The Influence of Geometric Parameters of 3D Printed Structured Beds on Hydrodynamic Characteristics of Trickle-Bed Reactor
The study examines a parametric set of POCS structures, where cubic cell is the basic element. The parameters such as strut diameter sd and cell size cs were varied1. These modifications are ...
Finite element approximation of fluid structure interaction using Taylor-Hood and Scott-Vogelius elements
Vacek, Karel; Sváček, P.
2024 - English
This paper addresses the problem of fluid flow interacting a vibrating solid cylinder described by one degree of freedom system and with fixed airfoil. The problem is described by the incompressible Navier-Stokes equations written in the arbitrary Eulerian-Lagrangian (ALE) formulation. The ALE mapping is constructed with the use of a pseudo-elastic approach. The flow problem is numerically approximated by the finite element method (FEM). For discretization of the fluid flow, the results obtained by both the Taylor-Hood (TH) element and the Scott-Vogelius (SV) finite element are compared. The TH element satisfies the Babuška-Brezzi inf-sup condition, which guarantees the stability of the scheme. In the case of the SV element the mesh, that is created as a barycentric refinement of regular triangulation, is used to satisfy the Babuška-Brezzi condition. The numerical results for two benchmark problems are shown.
Keywords:
finite element method; arbitrary Lagrangian-Eulerian method; Scott-Vogelius element; Taylor-Hood element
Available in digital repository of the ASCR
Finite element approximation of fluid structure interaction using Taylor-Hood and Scott-Vogelius elements
This paper addresses the problem of fluid flow interacting a vibrating solid cylinder described by one degree of freedom system and with fixed airfoil. The problem is described by the incompressible ...
Podnikání jako mužský svět? Využívání kompetencí v podnikání sebezaměstnaných žen a mikropodnikatelek v ČR
Maříková, Hana; Švarcová, Markéta; Křížková, Alena
2024 - Czech
Fulltext is available at external website.
Podnikání jako mužský svět? Využívání kompetencí v podnikání sebezaměstnaných žen a mikropodnikatelek v ČR
The American origin of the French Revolution
Ottinger, Sebastian; Rosenberger, L.
2024 - English
We show that the French combatants’ exposure to the United States increased support for the French Revolution a decade later. French regions from which more American combatants originated had more revolts against feudal institutions, revolutionary societies, volunteers for the revolutionary army, and emigrants from the Old Regime’s elite. To establish causality, we exploit two historical coincidences: i) originally, a French army of seven and a half thousand was ready to sail, but one-third did not, ii) among those deployed, only some regiments were stationed in New England. Only combatants exposed to New England affected the French Revolution after their return.
Keywords:
institutional change; French Revolution; American War of Independence
Fulltext is available at external website.
The American origin of the French Revolution
We show that the French combatants’ exposure to the United States increased support for the French Revolution a decade later. French regions from which more American combatants originated had more ...
Survey expectations, adaptive learning and inflation dynamics
Rychalovska, Y.; Slobodyan, Sergey; Wouters, R.
2024 - English
The use of survey information on inflation expectations as an observable in a DSGE model can substantially refine identification of the shocks that drive inflation. Optimal integration of the survey information improves the model forecast for inflation and for other macroeconomic variables. Models with expectations based on an Adaptive Learning setup can exploit survey information more efficiently than their Rational Expectations counterparts. The resulting time-variation in the perceived inflation target, in inflation persistence, and in the sensitivity of inflation to various shocks provide a rich and consistent description of the joint dynamics of realized and expected inflation. Our framework produces a reasonable interpretation of the post-Covid inflation dynamics. Our learning model successfully identifies the more persistent nature of the recent inflation surge.
Keywords:
inflation; expectations; survey data
Fulltext is available at external website.
Survey expectations, adaptive learning and inflation dynamics
The use of survey information on inflation expectations as an observable in a DSGE model can substantially refine identification of the shocks that drive inflation. Optimal integration of the survey ...
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