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Boron-doped diamond electrodes in electroanalysis of reducible organic compounds
Vosáhlová, J.; Zavázalová, J.; Petrák, Václav; Schwarzová-Pecková, K.
2015 - English
Boron doped diamond (BDD) electrodes became a well-established tool in electroanalysis of oxidizable organic compounds, nevertheless their possibilities in electroanalysis of reducible compounds remain relatively unexploited. Thus, in this study the influence of the presence of oxygen, electrode pretreatment, and activation between individual scans for electroreduction of tartrazine and allura red (azo group), 5-nitroquinoline (nitro group and N-heterocycle), vanillin (aromatic aldehyde), and azidothymidine (azide group) using batch voltammetry was tested.
Keywords:
5-nitroquinoline; azo-dyes; boron-doped diamond; boron concentration; voltammetry; reduction
Available at various institutes of the ASCR
Boron-doped diamond electrodes in electroanalysis of reducible organic compounds
Boron doped diamond (BDD) electrodes became a well-established tool in electroanalysis of oxidizable organic compounds, nevertheless their possibilities in electroanalysis of reducible compounds ...
Boron-doped diamond electrodes in electroanalysis of reducible organic compounds
Vosáhlová, J.; Zavázalová, J.; Petrák, Václav; Schwarzová-Pecková, K.
2015 - English
Boron doped diamond (BDD) electrodes became a well-established tool in electroanalysis of oxidizable organic compounds; nevertheless their possibilities in electroanalysis of reducible compounds remain relatively unexploited. Thus, in this study the influence of the presence of oxygen, electrode pretreatment, and activation between individual scans for electroreduction of tartrazine and allura red (azo group), 5-nitroquinoline (nitro group and N-heterocycle), vanillin (aromatic aldehyde), and azidothymidine (azide group) using batch voltammetry was tested.
Keywords:
5-nitroquinoline; azo-dyes; boron-doped diamond; boron concentration; voltammetry; reduction
Available at various institutes of the ASCR
Boron-doped diamond electrodes in electroanalysis of reducible organic compounds
Boron doped diamond (BDD) electrodes became a well-established tool in electroanalysis of oxidizable organic compounds; nevertheless their possibilities in electroanalysis of reducible compounds ...
Interpretation of the C=O band of modified diamond nanoparticles by means of DFT theory
Jirásek, Vít; Kozak, Halyna; Remeš, Zdeněk; Kromka, Alexander
2015 - English
Diamond nanoparticles (DNPs) are an interesting class of nanomaterials, which has many unique properties. Their applications in medicine and molecular biology have been mentioned. The DNPs were reviewed in sense of their surface chemistry and a range of analytic techniques was pointed out. The experimental analysis can be enhanced by theoretical models based on the first principles. An approach to theoretical analysis of infrared spectra was introduced. As an example, a part of FTIR spectra of the oxidized DNPs was interpreted by means of the DFT theory. The calculation of the C=O stretch vibrational frequencies of carboxylic and anhydride groups on certain model clusters enabled to explain the shift and splitting of the measured spectral bands.
Keywords:
diamond nanoparticles; functionalized diamond surface; density functional theory; vibrational spectra; FTIR
Available at various institutes of the ASCR
Interpretation of the C=O band of modified diamond nanoparticles by means of DFT theory
Diamond nanoparticles (DNPs) are an interesting class of nanomaterials, which has many unique properties. Their applications in medicine and molecular biology have been mentioned. The DNPs were ...
Verification of the use of pva based nanofiber textiles as a rehabilitation for the structures attack by wood decaying fungi
Rácová, Z.; Ryparová, Pavla; Wasserbauer, R.; Nežerka, V.; Tesárek, Pavel; Demo, Pavel
2014 - English
The presented paper is focused on the investigation of antifungal properties of nanofiber PVA-based textiles with incorporated copper and silver ions. In particular, the ability to prevent the growth of Dry rot fungus (Serpula lacrymans) was studied in laboratory conditions. For that purpose, the Petri dishes with malt agar were inoculated with square cut-outs of seed stocks, consequently covered by the nanofiber textiles and kept in an incubator at 28 degrees C. The fungal growth had been monitored and recorded at regular intervals for 28 days. The comparison of the individual treatments (PVA, PVA + Ag, PVA + Cu, PVA + Ag + Cu) is finally discussed.\n
Keywords:
nanofiber textiles; dry rot fungus; PVA; metal ions
Available at various institutes of the ASCR
Verification of the use of pva based nanofiber textiles as a rehabilitation for the structures attack by wood decaying fungi
The presented paper is focused on the investigation of antifungal properties of nanofiber PVA-based textiles with incorporated copper and silver ions. In particular, the ability to prevent the growth ...
Highly luminescent nanophosphors - new physics, technologies and applications
Nikl, Martin; Čuba, V.; Bárta, J.; Jarý, Vítězslav
2014 - English
The application of radiation synthesis in the manufacturing nanopowders of binary and ternary oxide nanophosphors is reviewed. Technological routes are described: irradiation of specific solutions containing soluble metal salts and OH radical scavenger by UV or ionizing radiation results in the formation of finely dispersed solid phase which is separated from the solution and subsequently converted by further thermal treatment into crystalline nanopowders with typical dimension of grains of several tens of nanometers. Doped ZnO, Y2O3, Y3Al5O12, Lu3Al5O12 and Gd3(Ga,Al)5O12 nanophosphors were prepared and their luminescence and scintillation characteristics were measured. In the photoluminescence decay of doped garnets the distinct effect of nanosized grains was found consisting in the slowing-down of the decay due to the change of effective refractive index.
Keywords:
scintillator; phosphor; radiation method; nanocrystals; garnet; ZnO; Y.sub.2./sub.O.sub.3./sub.; rare earth dopants
Available at various institutes of the ASCR
Highly luminescent nanophosphors - new physics, technologies and applications
The application of radiation synthesis in the manufacturing nanopowders of binary and ternary oxide nanophosphors is reviewed. Technological routes are described: irradiation of specific solutions ...
Electronic excitation energy transfer between quasi-zero-dimensional systems
Král, Karel; Menšík, Miroslav
2014 - English
Electronic excitation energy transfer is studied theoretically within a prototype system of quantum dots using the excitonic representation of the electronic states of two quasi-zero dimensional subsystems, between which the excitation energy is transferred in a process treated as an irreversible kinetic phenomenon. The electron-phonon interaction is used to circumvent the energy conservation problem, especially when considering the uphill and downhill excitation transfer processes. The theory is studied upon utilizing a simplified model of two interacting quantum dots, both coupled to their environment. The theoretical approach is documented by numerical calculations. The results could be relevant to various cases of the electronic excitation energy transfer between quasi zero dimensional nanostructures.
Keywords:
quantum dots; energy transfer; electron-phonon interaction
Available at various institutes of the ASCR
Electronic excitation energy transfer between quasi-zero-dimensional systems
Electronic excitation energy transfer is studied theoretically within a prototype system of quantum dots using the excitonic representation of the electronic states of two quasi-zero dimensional ...
Algicidal properties nanofibrous fabrics doped by metals
Ryparová, Pavla; Wasserbauer, R.; Rácová, Z.; Demo, Pavel; Tesárek, Pavel
2014 - English
The paper presents a novel protection against algae by nanofiber fabrics doped with metal ions. Nanofiber textiles were prepared by electrospinning on the Nanospider LB 500 device, equipped with cylindrical electrodes of a length 600 mm and electrode distance about 140 mm. The produced nanofiber textiles had a specific weight between 2 and 4 g/m2. The entire surface was covered with algae commonly accompanied by bacteria. The sample had placed in the middle of circular dishes having the diameter 20 mm. The cultivation took place at light environment in common laboratory conditions. Algicidal effect was evaluated as the resulting halo size and quality around the sample. The PVA treated sample had not produce any halo effect, unlike the samples with the addition of metal salts (AgNO3, CuSO4 center dot 5H(2)O) that exhibited the halo effect dependent on the concentration the salts, usually ranging from 0.3-2 mm, giving the evidence about their algicidal properties.\n
Keywords:
algicidal properties; polymer nanofibers; dispersed nanoparticles; metal nanoparticles; stone
Available at various institutes of the ASCR
Algicidal properties nanofibrous fabrics doped by metals
The paper presents a novel protection against algae by nanofiber fabrics doped with metal ions. Nanofiber textiles were prepared by electrospinning on the Nanospider LB 500 device, equipped with ...
Controlled structuring of self-assembled polystyrene microsphere arrays by two different plasma systems
Domonkos, Mária; Ižák, Tibor; Stolcova, L.; Proška, J.; Kromka, Alexander
2014 - English
In this study we present a successful manipulation of microspheres by reactive ion etching (RIE). A self-assembled monolayer close-packed array of monodisperse polystyrene microspheres (PM) with diameter of 471 nm was used as the primary template. The PM templates were processed in two different RIE systems: (i) capacitively coupled radiofrequency plasma (CCP) and (ii) dual plasma system which combines CCP and pulsed linear-antenna microwave plasma (PLAMWP). The influence of process conditions on the PM geometry was systematically studied by scanning electron microscopy (SEM). It was found out that choosing optimal parameters results in a tunable diameter of PM with various shapes (from spheres to pyramid-like structures) while keeping their periodic hexagonal ordering.
Keywords:
nanosphere lithography; reactive ion etching; pulsed linear-antenna microwave plasma; polystyrene microspheres; Langmuir-Blodgett monolayers
Available at various institutes of the ASCR
Controlled structuring of self-assembled polystyrene microsphere arrays by two different plasma systems
In this study we present a successful manipulation of microspheres by reactive ion etching (RIE). A self-assembled monolayer close-packed array of monodisperse polystyrene microspheres (PM) with ...
Safety aspects of usage of flammable and toxic gases in high power laser accelerator experiments
Procházka, Petr; Prokůpek, J.; Perales, B.
2014 - English
High power laser accelerators are promising technologies that can effectively decrease the space and potentially cost of the particle acceleration experiments. For many of them there is a technical demand to use flammable and toxic gases as targets for lasers or for accelerated particles. Their usage, however, brings many challenges for design of the technology and safety management system of the facility.
Keywords:
high power laser; accelerator
Available at various institutes of the ASCR
Safety aspects of usage of flammable and toxic gases in high power laser accelerator experiments
High power laser accelerators are promising technologies that can effectively decrease the space and potentially cost of the particle acceleration experiments. For many of them there is a technical ...
Comparative study on functionalization of NCD films with amine groups
Artemenko, Anna; Kozak, Halyna; Stuchlík, Jiří; Biederman, H.; Kromka, Alexander
2014 - English
Two plasma-based processes for functionalization of oxygen or hydrogen terminated NCD surfaces with amino groups were compared. The first process was based on deposition of thin (8 nm) amine containing plasma polymer by RF magnetron sputtering of Nylon target in Ar/N-2 working gas mixture. RF plasma treatment in NH3 for 10 minutes was used in the second process. The properties of NCD films before and after amination were characterized by scanning electron microscopy (SEM), wettability measurements, spectral ellipsometry, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and current-voltage (I-V) measurements. The presence of nitrogen (and thus amino groups) on the surface was confirmed by XPS measurements in both cases. The obtained results indicated that NCD surface functionalization from amine containing plasma polymer by RF magnetron sputtering is an alternative technological solution for successful functionalization of diamond surfaces for biosensor applications.
Keywords:
diamond; amino functionalization; XPS; surface conductivity
Available at various institutes of the ASCR
Comparative study on functionalization of NCD films with amine groups
Two plasma-based processes for functionalization of oxygen or hydrogen terminated NCD surfaces with amino groups were compared. The first process was based on deposition of thin (8 nm) amine ...
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