Chemical Composition of PM2.5 at Rural Backround Site Košetice
Schwarz, Jaroslav; Havránek, Vladimír
2011 - English
PM2.5 generally represents fine fraction of atmospheric aerosol. Fine particles may remain in the atmosphere for days or even weeks and therefore they may be transported over long distances. Moreover, they may increase the background levels of atmospheric aerosol mass far from their origin. They have important adverse health effects and in the same time, they influence climate due to their direct and indirect effects on Earth radiative balance. To know the origin of PM2.5 aerosol, its chemical composition can serve as the diary of contacts with aerosol sources and transformations. Therefore it is necessary to study PM2.5 chemical composition if the fine aerosol sources should be revealed. A rural background site study can serve as a basis enabling to determine the real influence of larger sources like cities or an industry.
Keywords:
PM2.5; elemental composition; chemical composition
Available at various institutes of the ASCR
Chemical Composition of PM2.5 at Rural Backround Site Košetice
PM2.5 generally represents fine fraction of atmospheric aerosol. Fine particles may remain in the atmosphere for days or even weeks and therefore they may be transported over long distances. Moreover, ...
Critical Notes on Heterogeneous Photocatalysis on TiO2 Photocatalysts
Klusoň, Petr; Hejda, S.
2011 - English
In our recent works we described different types of titania based materials used as either colloids or thin films. These were functionally characterized in photo-induced electrochemical measurements and/or in photocatalytic oxidations. Special attention was paid to the effect of organized internal structure induced by templating principles as an alternative to plasma enhanced physical methods. Considerable work has also been undertaken on research of porphyrine based photoactive macromolecules, which are efficient producers of singlet oxygen species upon well defined illumination.
Keywords:
titanium oxide; heterogeneous photocatalysis; thin films
Available at various institutes of the ASCR
Critical Notes on Heterogeneous Photocatalysis on TiO2 Photocatalysts
In our recent works we described different types of titania based materials used as either colloids or thin films. These were functionally characterized in photo-induced electrochemical measurements ...
Carbosilane Dendrimers Containing Titanium Complexes on Their Periphery
Strašák, Tomáš; Čermák, Jan
2011 - English
Keywords:
carbosilane dendrimers; titanium complexes
Available on request at various institutes of the ASCR
Carbosilane Dendrimers Containing Titanium Complexes on Their Periphery
Excimer Laser-Induced CVD of Carbon Encapsulated Cobalt Nanoparticles
Fajgar, Radek; Maryško, Miroslav; Dřínek, Vladislav; Kupčík, Jaroslav; Šubrt, Jan
2011 - English
Decomposition of acetylene / Co(CO)(3)(NO)mixtures induced by excimer ArF laser pulses is an efficient technique for preparation of amorphous cobalt nanoparticles encapsulated in carbon. Vacuum heating up to 900 degrees C leads to crystallization the metal core. The cobalt core crystallizes in a face-centered cubic (beta) form as revealed by X-ray and electron diffraction techniques and carbon affords graphite outer part. Properties of the Co(core) - carbon(shell)nanocomposites were examined by spectroscopy and microscopy techniques. Magnetization studies revealed paramagnetic behavior of the as-prepared amorphous deposit and superparamagnetic behavior of the annealed samples.
Keywords:
amorphous cobalt nanoparticles; carbon encapsulation; magnetic properties
Available at various institutes of the ASCR
Excimer Laser-Induced CVD of Carbon Encapsulated Cobalt Nanoparticles
Decomposition of acetylene / Co(CO)(3)(NO)mixtures induced by excimer ArF laser pulses is an efficient technique for preparation of amorphous cobalt nanoparticles encapsulated in carbon. Vacuum ...
Adsorption Assisted Ion Exchanger Catalyst for Fatty Acid Esterification
Jeřábek, Karel; Holub, Ladislav; Hanková, Libuše; Corain, B.; Centomo, P.; Zecca, M.
2011 - English
Keywords:
fatty acid; esterification
Available at various institutes of the ASCR
Adsorption Assisted Ion Exchanger Catalyst for Fatty Acid Esterification
Optimized Doped Titania for Photocatalysis Applications
Krejčíková, Simona; Kočí, K.; Obalová, L.; Čapek, L.; Šolcová, Olga
2011 - English
This study is focused on preparation and characterization of the specially designed TIO2 and its modified versions (doped by metal) suitable for photodegradations of organic pollutants.
Keywords:
titanium dioxide; siver; photocatalysis
Available at various institutes of the ASCR
Optimized Doped Titania for Photocatalysis Applications
This study is focused on preparation and characterization of the specially designed TIO2 and its modified versions (doped by metal) suitable for photodegradations of organic pollutants.
Domain Averaged Fermi hole Orbitals for Extended Systems
Baranov, A.I.; Kohout, M.; Ponec, Robert
2011 - English
Current contribution presents the results of DAFH orbital analysis for several simple model systems like hydrogen lattices as well as for prototypic real solids with covalent, ionic and metallic bonding.
Keywords:
domain averaged fermi holes; bonding in solids
Available at various institutes of the ASCR
Domain Averaged Fermi hole Orbitals for Extended Systems
Current contribution presents the results of DAFH orbital analysis for several simple model systems like hydrogen lattices as well as for prototypic real solids with covalent, ionic and metallic ...
Theoretical Interpretation of Enantioselectivity Trends in (R)-Ru-BINAP Catalyzed Hydrogenation of Methylacetoacetate in the QAS Ionic Liquid Phase
Dytrych, Pavel; Klusoň, Petr; Floriš, Tomáš; Lísal, Martin; Slater, M.
2011 - English
An essential part of this work was focused on the role of the alkyl chain length in NR 222Tf2N and its reflection in the evaluated kinetic parameters. For this screening NR 222Tf2N was mixed with methanol using the one-to-one weight ratio.
Keywords:
kinetic parameters; molecular simulation methods; evaluation
Available at various institutes of the ASCR
Theoretical Interpretation of Enantioselectivity Trends in (R)-Ru-BINAP Catalyzed Hydrogenation of Methylacetoacetate in the QAS Ionic Liquid Phase
An essential part of this work was focused on the role of the alkyl chain length in NR 222Tf2N and its reflection in the evaluated kinetic parameters. For this screening NR 222Tf2N was mixed with ...
A New Look on the Nernst Model in Electrochemistry
Wein, Ondřej
2011 - English
The present paper is inspired by the electrodiffusion (ED) flow measurement, utilizing the limiting-diffusion regime (LDR) in two-electrode ED cells. The electrochemical testing and calibrations of the ED cells is based on two standard electrochemical techniques - quasi-steady voltammetry and voltage-step transient. Recently published theory of the voltage-step transient under simultaneous effect of Faradaic and Ohmic resistances is based on a suitably extended Nernst model. An analogous theory of the voltammetric experiment is presented here.
Keywords:
nernst model of diffusion layer; primary current distribution; voltammetric curve
Available at various institutes of the ASCR
A New Look on the Nernst Model in Electrochemistry
The present paper is inspired by the electrodiffusion (ED) flow measurement, utilizing the limiting-diffusion regime (LDR) in two-electrode ED cells. The electrochemical testing and calibrations of ...
Kogenerace s využitím biomasy, vhodné výkony a možnosti efektivního využití tepla
Svoboda, Karel
2011 - English
Výhody a nevýhody kogenerace na bázi biomasy jsou srovnány se spolu-spalováním biomasy s fosilními palivy (uhlím). Vhodná paliva na bázi biomasy pro kogeneraci zahrnují hlavně dřevo a slámu, organické odpady, kaly z čistíren odpadních vod, odpadní rostlinné oleje a bioplyn. Spalování a zplyňování jsou nejpoužívanější termické procesy pro ko-generaci tepla a elektrické energie. Motory a plynové turbíny s vnitřním nebo vnějším spalováním, parní nebo ORC turbíny jsou nejobvyklejšími metodami pro kogeneraci. Palivové články vhodné pro kogeneraci jsou stále ve vývoji.
Keywords:
biomass; cogeneration; efficiency
Available at various institutes of the ASCR
Kogenerace s využitím biomasy, vhodné výkony a možnosti efektivního využití tepla
Výhody a nevýhody kogenerace na bázi biomasy jsou srovnány se spolu-spalováním biomasy s fosilními palivy (uhlím). Vhodná paliva na bázi biomasy pro kogeneraci zahrnují hlavně dřevo a slámu, ...
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