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TESTING THE METHOD OF MULTIPLE SCALES AND THE AVERAGING PRINCIPLE FOR MODEL PARAMETER ESTIMATION OF QUASIPERIODIC TWO TIME-SCALE MODELS
Papáček, Štěpán; Matonoha, Ctirad
2023 - English
Some dynamical systems are characterized by more than one timescale, e.g. two well separated time-scales are typical for quasiperiodic systems. The aim of this paper is to show how singular perturbation methods based on the slow-fast decomposition can serve for an enhanced parameter estimation when the slowly changing features are rigorously treated. Although the ultimate goal is to reduce the standard error for the estimated parameters, here we test two methods for numerical approximations of the solution of associated forward problem: (i) the multiple time-scales method, and (ii) the method of averaging. On a case study, being an under-damped harmonic oscillator containing two state variables and two parameters, the method of averaging gives well (theoretically predicted) results, while the use of multiple time-scales method is not suitable for our purposes.
Keywords:
Dynamical system; Singular perturbation; Averaging; Parameter estimation; Slow-fast decomposition; Damped oscillations
Fulltext is available at external website.
TESTING THE METHOD OF MULTIPLE SCALES AND THE AVERAGING PRINCIPLE FOR MODEL PARAMETER ESTIMATION OF QUASIPERIODIC TWO TIME-SCALE MODELS
Some dynamical systems are characterized by more than one timescale, e.g. two well separated time-scales are typical for quasiperiodic systems. The aim of this paper is to show how singular ...
GA 19-07635S: Outputs and Results
Rehák, Branislav
2023 - English
This manuscript aims to deliver a survey of results obtained during the solution of the project No. GA19-07635S of the Czech Science Foundation. The timespan dedicated to the work on this project was 1.3.2019 - 30.6.2022. The main area dealt with were\nnonlinear multi-agent systems and their synchronization, further, attention was paid to some auxiliary results in the area of nonlinear observers. This Report briefly introduces the Project, provides a summary of the results obtained and also sketches an outline how these results will be applied and extended in future.
Keywords:
multi-agent systems; nonlinear multi-agent systems; synchronization
Fulltext is available at external website.
GA 19-07635S: Outputs and Results
This manuscript aims to deliver a survey of results obtained during the solution of the project No. GA19-07635S of the Czech Science Foundation. The timespan dedicated to the work on this project was ...
Metodika identifikace zdrojů znečišťování pomocí PMF pro strategické rozhodování při ochraně ovzduší – aktualizace 2023
Horník, Štěpán; Sýkora, Jan; Pokorná, Petra
2023 - Czech
Předkládaná metodika navrhuje využití spektroskopie nukleární magnetické rezonance (NMR) jako další analytické techniky pro identifikaci sloučenin v atmosférických aerosolech. Tato technika umožňuje výrazně zvýšit počet stanovovaných látek a tfm i případný počet markerů, které lze následně ve spojení s jinými metodami využít pro identifikaci zdrojů znečištění ovzduší pomocí pokročilé statistické analýzy. Mezi markery stanovované pomocí\nNMR spektroskopie náleží různé organické kyseliny, sulfonové kyseliny nebo sacharidy, které jsou charakteristické pro příslušné zdroje znečištění. Aktualizovaná metodika také představuje identifikaci biogenního zdroje, který předcházející metodiky nedokázaly stanovit. The presented methodology proposes utilizatíon of the spectroscopy of nuclear magnetic resonance (NMR) as another analytical technique for the identification of compounds in atmospheric aerosols. This technique makes significantly increases the number of deterined substances and thus a number of possible markers, which can be subsequently used together with other methods to identify sources of air pollution using advanced statistical\nanalysis. Among the markers determined by NMR spectroscopy there are several organic and sulfonic acids or carbohydrates, wich are characteristic for relevant sources of air pollution. The updated methodology also shows the identification of a biogenic source that previous methodologies were not able to determine.
Keywords:
NMR spectroscopy; atmospheric aerosols; markers
Available on request at various institutes of the ASCR
Metodika identifikace zdrojů znečišťování pomocí PMF pro strategické rozhodování při ochraně ovzduší – aktualizace 2023
Předkládaná metodika navrhuje využití spektroskopie nukleární magnetické rezonance (NMR) jako další analytické techniky pro identifikaci sloučenin v atmosférických aerosolech. Tato technika umožňuje ...
Inflation expectations in the wake of the war in Ukraine
Afunts, Geghetsik; Cato, M.; Schmidt, T.
2023 - English
Russia's invasion of Ukraine is posing a range of new challenges to the global economy, including affecting the inflation expectations of individuals. In this paper, we aim to quantify the effect of the invasion on short- and long-term inflation expectations of individuals in Germany. We use microdata from the Bundesbank Online Panel - Households (BOP-HH), for the period from February 15th to March 29th, 2022. Treating the unanticipated start of the war in Ukraine on the 24th of February 2022 as a natural experiment, we find that both short- and long-term inflation expectations increased as an immediate result of the invasion. Long-term inflation expectations increased by around 0.4 percentage points, while the impact on short-term inflation expectations was more than twice as large - around one percentage point. Looking into the possible mechanisms of this increase, we suggest that it can be partially attributed to individuals’ fears of soaring energy prices and increasing pessimism about economic trends in general. Our results indicate that large economic shocks can have a substantial impact on both short and long-term inflation expectations.
Keywords:
inflation expectations; Russian invasion of Ukraine; survey
Fulltext is available at external website.
Inflation expectations in the wake of the war in Ukraine
Russia's invasion of Ukraine is posing a range of new challenges to the global economy, including affecting the inflation expectations of individuals. In this paper, we aim to quantify the effect of ...
Vývoj postojů české veřejnosti k válečným uprchlíkům z Ukrajiny
Münich, Daniel; Protivínský, Tomáš
2023 - Czech
Po vojenském útoku Ruska na Ukrajinu koncem února 2022 v Česku převládla atmosféra solidarity a většina Čechů přijímání válečných uprchlíků podporovala. Tato podpora do konce listopadu klesla zhruba o čtvrtinu. Podobně se zhoršovala vnímaná míra integrace Ukrajinců do české společnosti. Změna postojů české společnosti v čase však nevycházela primárně z osobní zkušenosti a z prožitého příchodu uprchlíků, ale souvisela spíše s postupně opadávajícím zájmem po vypuknutí konfliktu a prvotním šoku. Ačkoli se integrace Ukrajinců v některých dimenzích ve druhé polovině roku 2022 reálně zlepšila, například ve školách nebo na trhu práce, do vnímání české společnosti se tyto dílčí pokroky nepromítly. In the wake of Russia’s military assault on Ukraine at the end of February 2022, an atmosphere of solidarity prevailed in the Czech Republic and most of the Czech population supported the country’s intake of war refugees. By the end of November 2022, that support had fallen by approximately one quarter. Czechs’ perceptions of how well integrated Ukrainians were into Czech society worsened similarly. This change in Czech public attitudes over time did not, however, stem primarily from personal or first hand experience of welcoming refugees, rather, it was related to a gradual decrease in public interest in the conflict after the initial shock of it first beginning. Although several aspects of Ukrainian refugees’ integration improved in real terms in the second half of 2022, for example in relation to schools and to the labour market, this progress was not reflected in Czech public opinion.
Keywords:
Ukrainian refugees; views and attitudes; Czech Republic
Fulltext is available at external website.
Vývoj postojů české veřejnosti k válečným uprchlíkům z Ukrajiny
Po vojenském útoku Ruska na Ukrajinu koncem února 2022 v Česku převládla atmosféra solidarity a většina Čechů přijímání válečných uprchlíků podporovala. Tato podpora do konce listopadu klesla zhruba o ...
Snížila by větší bytová výstavba cenový růst nemovitostí v letech 2013–2021? Pravděpodobně ne
Šustek, R.; Zapletalová, Lucie
2023 - Czech
Tato studie představuje snadno aplikovatelnou metodu pro studium vývoje cen rezidenčních nemovitostí a faktorů, které je ovlivňují. Obsahem studie je popis základní logiky metody, výsledky jejího použití k analýze růstu cen nemovitostí v ČR v letech 2013–2021 a výsledky analýzy možných budoucích scénářů. This study presents an easily applicable method for the study of price trends in residential property markets and the factors that affect them. The study describes the basic reasoning behind the method and presents results of using it to analyse house price increases in the Czech Republic during the period of 2013-2021, and to analyse various future housing market scenarios.
Keywords:
residential property markets; house prices; Czech Republic
Fulltext is available at external website.
Snížila by větší bytová výstavba cenový růst nemovitostí v letech 2013–2021? Pravděpodobně ne
Tato studie představuje snadno aplikovatelnou metodu pro studium vývoje cen rezidenčních nemovitostí a faktorů, které je ovlivňují. Obsahem studie je popis základní logiky metody, výsledky jejího ...
A polarizable reference electrode
Mareček, Vladimír
2023 - English
New concept of a reference electrode for electrochemical systems resolves a problem of a poor \npotential stability of refence electrodes based on the distribution of a strongly \nhydrophobic common cation between two immiscible electrolyte solutions (TTTES). The use of a \npolarizable metal electrode instead of a classical reference electrode is demonstrated in \n a modified conventional four-electrode cell with TTTES. A simple battery operated potentiostat \ncontrols the working electrode potential in a three-electrode configuration. The working metal \nelectrode then serves as a polarizable reference organic solvent electrode in a four-electrode \nsystem for the polarization of the water/organic solvent interface.\n\n
Keywords:
reference electrode; liquid/liquid interface; chloride extraction
Available on request at various institutes of the ASCR
A polarizable reference electrode
New concept of a reference electrode for electrochemical systems resolves a problem of a poor \npotential stability of refence electrodes based on the distribution of a strongly ...
Elektrochemické studium pH závislých redoxních vlastností komplexů mědi s aza-makrocyklickými ligandy
Koláčná, Lucie; Maďar, M.; Kubíček, V.; Ludvík, Jiří
2023 - Czech
Molekulární elektronika je progresivní směr moderní materiálové chemie. Zabývá se vývojem\nelektronických prvků na úrovni jedné molekuly. Nejdůmyslnější molekulární elektroniku\nnajdeme v přírodě v podobě metaloenzymů. Jedním ze směrů výzkumu jejich modelů jsou\nkomplexy různě substituovaných azamakrocyklů. Předností těchto molekul je jejich stabilita a\ndobře definovaná syntéza. Investigated Cu(II) complexes are based on plain or cross-bridged cyclam. The\nelectrochemically inactive cyclam was modified by carboxylate, phosphonate, or phenolate\npendant arms. Cu(II) represents the main redox center of the complexes. Modification of the\nligand causes a changed pattern of complex redox response in buffered aqueous solution.\nIrreversible Cu(II) reduction results in complex decomposition to amalgamated copper and\nligand in excess. After Cu(0) electrochemical in situ re-oxidation, copper and ligand are recomplexed.\nComplexes undergo isomerization, accelerated by increasing the temperature. The\ninfluence of pH on complex isomerization and the reversibility of its reduction was described.
Keywords:
cyclam; Cu(II) complexes; pendant arms
Available on request at various institutes of the ASCR
Elektrochemické studium pH závislých redoxních vlastností komplexů mědi s aza-makrocyklickými ligandy
Molekulární elektronika je progresivní směr moderní materiálové chemie. Zabývá se vývojem\nelektronických prvků na úrovni jedné molekuly. Nejdůmyslnější molekulární elektroniku\nnajdeme v přírodě v ...
Determination of Selected Natural Psychoactive Substances in Organic Matrices at 3D Printed Electrodes
Choińska-Mlynarczyk, Marta; Šestáková, Ivana; Navrátil, Tomáš
2023 - English
Psilocybin and its derivative psilocin are popular psychoactive substances both as experimental\ntreatments in clinical trials and as illicit drugs. Their potential ability to influence the human\nbrain entails the need for a fast, inexpensive, selective, and sensitive method of their\ndetermination. The aim of our study was the development of new 3D-printed electrodes which\nfulfill these demands and are useful for medical, toxicological, and forensic purposes.\nSuccessful development allows determining in real matrices (human plasma and dried\nmushrooms) concentrations of the order of 1 μmol dm-3.\n
Keywords:
natural psychoactive substances; 3D-printed electrodes; psilocin; psilocybin
Available on request at various institutes of the ASCR
Determination of Selected Natural Psychoactive Substances in Organic Matrices at 3D Printed Electrodes
Psilocybin and its derivative psilocin are popular psychoactive substances both as experimental\ntreatments in clinical trials and as illicit drugs. Their potential ability to influence the ...
Utilization of electrochemically induced cleavage of various sulfonimides
Salvadori, Karolína
2023 - English
In this work, we describe the unexpected electrochemical cleavage of sulfonimides, providing a direct pathway to corresponding sulfonamides. For this purpose, 16 substances were synthesized and tested, reflecting the influence of different electron effects of -SO2Ph-R substituents, and the impact of the number of nosyl units present in molecules. In the case of octakis-nosylated calixarenes, the electrochemical cleavage via direct potential-controlled electrolysis was compared with conventional organic synthetic procedures. After electrolysis, all prepared sulfonamides were isolated in excellent yields.
Keywords:
sulfonimides; green chemistry procedures; electrochemisty
Available in a digital repository NRGL
Utilization of electrochemically induced cleavage of various sulfonimides
In this work, we describe the unexpected electrochemical cleavage of sulfonimides, providing a direct pathway to corresponding sulfonamides. For this purpose, 16 substances were synthesized and ...
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