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GA 19-07635S: Outputs and Results
Rehák, Branislav
2023 - anglický
This manuscript aims to deliver a survey of results obtained during the solution of the project No. GA19-07635S of the Czech Science Foundation. The timespan dedicated to the work on this project was 1.3.2019 - 30.6.2022. The main area dealt with were\nnonlinear multi-agent systems and their synchronization, further, attention was paid to some auxiliary results in the area of nonlinear observers. This Report briefly introduces the Project, provides a summary of the results obtained and also sketches an outline how these results will be applied and extended in future.
Klíčová slova:
multi-agent systems; nonlinear multi-agent systems; synchronization
Dokument je dostupný na externích webových stránkách.
GA 19-07635S: Outputs and Results
This manuscript aims to deliver a survey of results obtained during the solution of the project No. GA19-07635S of the Czech Science Foundation. The timespan dedicated to the work on this project was ...
Application of In situ TR Spectroelectrochemical Techniques in Determination of Redox Mechanism of Bioactive Compounds
Sokolová, Romana; Jiroušková, Eliška; Degano, I.; Wantulok, J.; Nycz, J.
2023 - anglický
The electron transfer reactions play an important role in many natural processes. Reactions such as \ndissociation, protonation, and reactions with water and other small molecules often occur in \nbiotransformation. The reaction schemes involving these chemical reactions coupled to the \nelectron transfer can be determined by cyclic voltammetry. Additionally, in \nsitu spectroelectrochemistry can efficiently contribute to the determination of oxidation or \nreduction mechanism. This technique provides information about the electroactive chromophore during \nthe redox process allowing to identification the first reaction intermediates. The final reaction \nproducts were identified by chromatographic techniques. This study represents a key role of TR \nspectroelectrochemistry in the determination of reaction intermediates in the case of \n1,10- phenanthroline derivative substituted by bioactive phenothiazine unit and \ndrug 3- fluorophenmetrazine (2-(3-fluorophenyl)-3-methylmorpholine, 3-FPM). Co pound 3-FPM\nhave recently appeared as the new psychoactive substance in the drug market.\n
Klíčová slova:
IR spectroelectrochemistry; psychoactive substances; oxidation mechanism
Plné texty jsou dostupné na vyžádání prostřednictvím repozitáře Akademie věd.
Application of In situ TR Spectroelectrochemical Techniques in Determination of Redox Mechanism of Bioactive Compounds
The electron transfer reactions play an important role in many natural processes. Reactions such as \ndissociation, protonation, and reactions with water and other small molecules often occur in ...
A polarizable reference electrode
Mareček, Vladimír
2023 - anglický
New concept of a reference electrode for electrochemical systems resolves a problem of a poor \npotential stability of refence electrodes based on the distribution of a strongly \nhydrophobic common cation between two immiscible electrolyte solutions (TTTES). The use of a \npolarizable metal electrode instead of a classical reference electrode is demonstrated in \n a modified conventional four-electrode cell with TTTES. A simple battery operated potentiostat \ncontrols the working electrode potential in a three-electrode configuration. The working metal \nelectrode then serves as a polarizable reference organic solvent electrode in a four-electrode \nsystem for the polarization of the water/organic solvent interface.\n\n
Klíčová slova:
reference electrode; liquid/liquid interface; chloride extraction
Plné texty jsou dostupné na vyžádání prostřednictvím repozitáře Akademie věd.
A polarizable reference electrode
New concept of a reference electrode for electrochemical systems resolves a problem of a poor \npotential stability of refence electrodes based on the distribution of a strongly ...
Determination of Selected Natural Psychoactive Substances in Organic Matrices at 3D Printed Electrodes
Choińska-Mlynarczyk, Marta; Šestáková, Ivana; Navrátil, Tomáš
2023 - anglický
Psilocybin and its derivative psilocin are popular psychoactive substances both as experimental\ntreatments in clinical trials and as illicit drugs. Their potential ability to influence the human\nbrain entails the need for a fast, inexpensive, selective, and sensitive method of their\ndetermination. The aim of our study was the development of new 3D-printed electrodes which\nfulfill these demands and are useful for medical, toxicological, and forensic purposes.\nSuccessful development allows determining in real matrices (human plasma and dried\nmushrooms) concentrations of the order of 1 μmol dm-3.\n
Klíčová slova:
natural psychoactive substances; 3D-printed electrodes; psilocin; psilocybin
Plné texty jsou dostupné na vyžádání prostřednictvím repozitáře Akademie věd.
Determination of Selected Natural Psychoactive Substances in Organic Matrices at 3D Printed Electrodes
Psilocybin and its derivative psilocin are popular psychoactive substances both as experimental\ntreatments in clinical trials and as illicit drugs. Their potential ability to influence the ...
Dynamics of Machines and Mechanical Systems with Interactions, DYMAMESI 2023
Zolotarev, Igor; Pešek, Luděk; Kozień, M. S.
2023 - anglický
The aim of the DYMAMESI is to facilitate the exchange of up to date information and knowledge among specialists in structural and multibody dynamics, in coupled interacting systems as aero-elasticity, hydro-elasticity, biomechanics, systems with feedbacks and mechatronics. The colloquium DYMAMESI 2021 is cofunded by the Strategy AV21 initiative of the Czech Academy of Sciences of the Czech Republic, and in 2021 will be hosted by Cracow University of Technology, Institute of Applied Mechanics, Section of Dynamics of Systems.
Klíčová slova:
dynamics; vibrations of mechanical systems; vibrodiagnostics; energy transformations
Plné texty jsou dostupné na jednotlivých ústavech Akademie věd ČR.
Dynamics of Machines and Mechanical Systems with Interactions, DYMAMESI 2023
The aim of the DYMAMESI is to facilitate the exchange of up to date information and knowledge among specialists in structural and multibody dynamics, in coupled interacting systems as aero-elasticity, ...
On the structure and values of betweenness centrality in dense betweenness-uniform graphs
Ghanbari, B.; Hartman, David; Jelínek, V.; Pokorná, Aneta; Šámal, R.; Valtr, P.
2023 - anglický
Betweenness centrality is a network centrality measure based on the amount of shortest paths passing through a given vertex. A graph is betweenness-uniform (BUG)if all vertices have an equal value of betweenness centrality. In this contribution, we focus on betweenness-uniform graphs with betweenness centrality below one. We disprove a conjecture about the existence of a BUG with betweenness value α for any rational numberαfrom the interval (3/4,∞) by showing that only very few betweenness centrality values below 6/7 are attained for at least one BUG. Furthermore, among graphs with diameter at least three, there are no betweenness-uniform graphs with a betweenness centrality smaller than one. In graphs of smaller diameter, the same can be shown under a uniformity condition on the components of the complement.
Klíčová slova:
betweenness; graphs
Plné texty jsou dostupné v digitálním repozitáři Akademie Věd.
On the structure and values of betweenness centrality in dense betweenness-uniform graphs
Betweenness centrality is a network centrality measure based on the amount of shortest paths passing through a given vertex. A graph is betweenness-uniform (BUG)if all vertices have an equal value of ...
Adaptation of methods for cyclo-stationary processes for noisy structural health data
Fischer, Cyril; Bayer, Jan; Náprstek, Jiří; Urushadze, Shota
2023 - anglický
In structural health analysis, various techniques, including indirect measurement via monitoring vehicles, often yield data with significant randomness and insufficient frequency separation. Conversely, the desired attributes under scrutiny are periodic in nature. Thus, methodologies designed to identify cyclo-stationary properties within noisy data can be adapted for such scenarios, assuming an adequate length of the recorded data.
Klíčová slova:
data analysis; cyclo-stationary processes; structural health monitoring
Plné texty jsou dostupné na jednotlivých ústavech Akademie věd ČR.
Adaptation of methods for cyclo-stationary processes for noisy structural health data
In structural health analysis, various techniques, including indirect measurement via monitoring vehicles, often yield data with significant randomness and insufficient frequency separation. ...
Consistency of mathematical and experimental model of the autoparametric system
Fischer, Cyril; Náprstek, Jiří
2023 - anglický
This paper presents a long-overdue comparison of data obtained from experimental investigation of a spherical vibration absorber with the results of two mathematical models of the motion of a heavy sphere in a spherical surface. It shows that the danger posed by the potentially unstable self-parametric nature of the mathematical system is not too great in the case of realistic configurations, and that the values of the parameters describing the realistic structures remain within intervals corresponding to the stable behaviour of the absorber.
Klíčová slova:
vibration absorber; rolling sphere; spherical surface; autoparametric system; structural health monitoring
Plné texty jsou dostupné na jednotlivých ústavech Akademie věd ČR.
Consistency of mathematical and experimental model of the autoparametric system
This paper presents a long-overdue comparison of data obtained from experimental investigation of a spherical vibration absorber with the results of two mathematical models of the motion of a heavy ...
Professional survey forecasts and expectations in DSGE models
Rychalovska, Y.; Slobodyan, Sergey; Wouters, R.
2023 - anglický
In this paper, we demonstrate the usefulness of survey data for macroeconomic analysis and propose a strategy to integrate and efficiently utilize information from surveys in the DSGE setup. We extend the set of observable variables to include the data on consumption, investment, output, and inflation expectations, as measured by the Survey of Professional Forecasters (SPF). By doing so, we aim to discipline the dynamics of model-based expectations and evaluate alternative belief models. Our approach to exploit the timely information from surveys is based on re-specification of structural shocks into persistent and transitory components. Due to the SPF, we are able to improve identification of fundamental shocks and predictive power of the model by separating the sources of low and high frequency volatility. Furthermore, we show that models with an imperfectly-rational expectation formation mechanism based on Adaptive Learning (AL) can reduce important limitations implied by the Rational Expectation (RE) hypothesis. More specifically, our models based on belief updating can better capture macroeconomic trend shifts and, as a result, achieve superior long-term predictions. In addition, the AL mechanism can produce realistic time variation in the transmission of shocks and perceived macro-economic volatility, which allows the model to better explain the investment dynamics. Finally, AL models, which relax the RE constraint of internal consistency between the agents’ and model forecasts, can reproduce the main features of agents’ predictions in line with SPF evidence and, at the same time, can generate improved model forecasts, thus diminishing possible inefficiencies present in surveys.
Klíčová slova:
expectations; survey data; adaptive learning
Dokument je dostupný na externích webových stránkách.
Professional survey forecasts and expectations in DSGE models
In this paper, we demonstrate the usefulness of survey data for macroeconomic analysis and propose a strategy to integrate and efficiently utilize information from surveys in the DSGE setup. We extend ...
Gender gap in reported childcare preferences among parents
Pertold, Filip; Sinani, S.; Šoltés, M.
2023 - anglický
The child penalty explains the majority of gender employment and wage gaps, however, less is known about the factors driving the child penalty itself. In this paper, we study the gender gap in childcare preferences as a potential factor that contributes to the child penalty. We surveyed Czech parents and elicited the minimal compensation they would require to stay home to care for a child. Mothers require less compensation for childcare than fathers. The estimated gender gap in childcare preferences is CZK 2,500 monthly, 7.6% of the median female wage, and cannot be explained by differences in labor market opportunities or prosocial motives to care for a family member. We further document widespread misperception of fathers’ preferences, as respondents incorrectly expect fathers to require less to care for a child than to care for an elderly parent.\n
Klíčová slova:
childcare; gender wage gap; gender employment gap
Dokument je dostupný na externích webových stránkách.
Gender gap in reported childcare preferences among parents
The child penalty explains the majority of gender employment and wage gaps, however, less is known about the factors driving the child penalty itself. In this paper, we study the gender gap in ...
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