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Chiral anion exchanger based on α-methylbenzylamine for enantioselective separation of racemic acids
Čížek, Jan
2023 - English
In this work, new enantioselective material based on α-methylbenzylamine as the chiral selector (recently utilized by our group in the preparation of chiral\nmembranes) covalently attached to Merrifield resin beads is proposed and discussed as a potentially cost-effective alternative to typically expensive stationary phase materials. It is shown that charged chiral methylbenzylamine works as an enantioselective anion exchanger potentially suitable for the separation of chiral acids, such as N–protected amino acid, or non-steroidal anti-inflammatory drugs (NSAID), such as ibuprofen. In a glass column chromatography experiment, racemic N–(tert–butoxycarbonyl) tryptophan was partially separated, reaching enantiomeric excess in eluates of around 10%.\n
Keywords:
chiral membranes; separation; racemic acids
Available in a digital repository NRGL
Chiral anion exchanger based on α-methylbenzylamine for enantioselective separation of racemic acids
In this work, new enantioselective material based on α-methylbenzylamine as the chiral selector (recently utilized by our group in the preparation of chiral\nmembranes) covalently attached to ...
Application of hydrodynamic cavitation in brewing
Štěrba, Jiří
2023 - English
The aim of this work is to apply these advantages in the brewery industry. In the field of beer brewing, we would like to investigate several phenomenona, such as the isomerization of bitter hop acids, the reduction of gluten concentration or the cell-walls breakdown.
Keywords:
brewery industry; hydrodynamic cavitation; experiments
Available in a digital repository NRGL
Application of hydrodynamic cavitation in brewing
The aim of this work is to apply these advantages in the brewery industry. In the field of beer brewing, we would like to investigate several phenomenona, such as the isomerization of bitter hop ...
Intercomparison of boundary layer and mixing layer height from models and ground-based measurements
Julaha, Kajal
2023 - English
In this study, we found that the boundary layer height tends to belower in ERA5 and timing for the daily peak also appears to differ\nas compared to ceilometer boundary layer data. In contrast, the ERA5 boundary layer observation was found to agree well with the mixing layer height obtained from the ceilometer. Whereas in comparison to HYSPLIT, GFS and GDAS, observations were found to agree well with ceilometer data while Reanalysis underestimated mixing layer height throughout the year. The seasonal changes in the boundary/mixing layer height were well captured by both models and the ceilometer.
Keywords:
planetary boundary layer; air pollution; measurements
Available in a digital repository NRGL
Intercomparison of boundary layer and mixing layer height from models and ground-based measurements
In this study, we found that the boundary layer height tends to belower in ERA5 and timing for the daily peak also appears to differ\nas compared to ceilometer boundary layer data. In contrast, the ...
INTRODUCTION TO PRAGUE AEROSOL CALIBRATION CENTER
Ondráček, Jakub; Roztočil, Petr
2023 - English
In general, the PACC offers a range of services, from calibration and consulting to methodology and technical development. Furthermore, the PACC has the capacity to organize and perform training for microphysical (including optical in the near future) aerosol in-situ instrumentation. The equipment at the PACC is fully in-line with the state of-the-art aerosol instrumentation (starting from various aerosol generators for welldefined nanoparticles, reference instruments, and newly designed calibration lines) and the laboratory space is flexible for various types of instrument calibration/verification/intercomparison or testing of newly developed, cutting-edge equipment.
Keywords:
calibration laboratory; ACTRIS; CPC
Available in a digital repository NRGL
INTRODUCTION TO PRAGUE AEROSOL CALIBRATION CENTER
In general, the PACC offers a range of services, from calibration and consulting to methodology and technical development. Furthermore, the PACC has the capacity to organize and perform training for ...
PM1 UNDER THE MICROSCOPE: MULTI-ANNUAL AEROSOL OPTICAL PROPERTIES AND SIZE DISTIRBUTION OBSERVATION AT PERI-URBAN ATMOSPHERIC SITE ATOLL
Suchánková, Lenka; Bourrianne, E.; De Fillipi, R.; De Brito, J.F.; Riffault, V.; Prokeš, R.; Holoubek, I.; Ždímal, Vladimír; Crumeyrolle, S.
2023 - English
Atmospheric aerosols (AA) belong to short-lived climate forcers with high spatial and temporal variability. Although the radiative effects of AA are greatest on regional scales, changes in aerosol emissions can induce long-term global climate effects (Szopa et al., 2021). Thus, the measurement of aerosol properties is essential for better understanding of aerosol’s impact on health and climate. Although several international projects and platforms have been monitoring AA properties worldwide (GAW, WMO, ACTRIS, EMEP, EUCAARI, etc., Pandolfi et al., 2018), only PM10 or PM2.5 cutoff sizes have been used for measurements, and information about PM1 particles is missing. The aim of this study is to present aerosol scattering properties with supporting data of absorption and particle number size distribution in PM1 in years 2018-2022 at peri-urban atmospheric site Atmospheric Observations in LiLLE (ATOLL) in Lille, France. This study is the first to present results dedicated to aerosol scattering properties at this site.
Keywords:
scattering coefficient; nephelometer; fossil fuel and biomass burning contribution
Available in a digital repository NRGL
PM1 UNDER THE MICROSCOPE: MULTI-ANNUAL AEROSOL OPTICAL PROPERTIES AND SIZE DISTIRBUTION OBSERVATION AT PERI-URBAN ATMOSPHERIC SITE ATOLL
Atmospheric aerosols (AA) belong to short-lived climate forcers with high spatial and temporal variability. Although the radiative effects of AA are greatest on regional scales, changes in aerosol ...
Recyklace solárních fotovoltaických panelů
Šperlich, Antonín
2023 - Czech
Dlouhodobé trendy ukazují zvyšující se instalovanou kapacitu solárních fotovoltaických elektráren. S tím je však také spojena velká produkce vyřazených panelů. Odhadované množství odpadních panelů se předpokládá mezi 60 a 80 miliony tun celosvětově okolo roku 2050. Takto velké objemy odpadů mohou tvořit zajímavý zdroj cenných látek, ale také nutnost recyklace kvůli životnímu prostředí. Příspěvek má za cíl popsat možnosti recyklace panelů a jejich využití ke stavbě reálné recyklační linky. Long-term trends show an increasing installed capacity of solar photovoltaic power plants. However, this is also associated with a large production of discarded panels. It is estimated that by 2050 there will be between 60 and 80 million tonnes of waste panels worldwide. Such large amounts of waste can be an \ninteresting source of valuable materials, but also need to be recycled for environmental reasons. The aim of this paper is to describe the possibilities of recycling panels and using them to build a real recycling line.
Keywords:
recycling; solar photovoltaic panels; technology design
Available in a digital repository NRGL
Recyklace solárních fotovoltaických panelů
Dlouhodobé trendy ukazují zvyšující se instalovanou kapacitu solárních fotovoltaických elektráren. S tím je však také spojena velká produkce vyřazených panelů. Odhadované množství odpadních panelů se ...
Detailed Investigation of Human Galectins -1 and -3 by employing selectively deoxyfluorinated N-acetyllactosamines
Kurfiřt, Martin
2023 - English
This work is focused on a detailed investigation of supramolecular recognition events between human galectins -1 and -3 and monodeoxyfluorinated N-acetyllactosamine probes, which were previously prepared in our laboratory. The recognition was studied using a combination of X-ray crystallography, isothermal titration calorimetry and several advanced NMR techniques, such as 19F T2-filter, 1H–1H STD, 1H–15N CSP or 19F EXSY. These techniques provided insight into the thermodynamics and kinetics of recognition and enabled us to uncover of subtle differences between both investigated galectins. Such differences could be potentially exploited in the selective targeting of individual galectins with important implications for the galectins-focused\npharmaceutic industry.
Keywords:
galectins; NMR techniques; pharmaceutic industry
Available in a digital repository NRGL
Detailed Investigation of Human Galectins -1 and -3 by employing selectively deoxyfluorinated N-acetyllactosamines
This work is focused on a detailed investigation of supramolecular recognition events between human galectins -1 and -3 and monodeoxyfluorinated N-acetyllactosamine probes, which were previously ...
The electrodiffusional theory for wall shear stress measurement by a two-strip probe: a journey to near-wall region hydrodynamics
Harrandt, Václav
2023 - English
This contribution deals with a new theory describing mass transport in the vicinity of the measuring two-segment strip probe. Analytical formulas for the mass transfer coefficients of the front and the rear electrodes were derived. At the same time, the correctness of these formulas was confirmed by the numerical solution of the convectiondiffusion transport equation.
Keywords:
transport phenomena; electrodes; wall shear stress
Available in a digital repository NRGL
The electrodiffusional theory for wall shear stress measurement by a two-strip probe: a journey to near-wall region hydrodynamics
This contribution deals with a new theory describing mass transport in the vicinity of the measuring two-segment strip probe. Analytical formulas for the mass transfer coefficients of the front and ...
(NE)ZÁVISLOST AKTIVACE AEROSOLU NA POZICI V OBLAKU
Zíková, Naděžda; Pokorná, Petra; Sedlák, Pavel; Sokol, Zbyněk; Ždímal, Vladimír
2023 - Czech
Na hoře Milešovka v České republice bylo provedeno pět in situ kampaní zaměřených na interakci aerosolu s oblakem, jejichž cílem bylo získat více informací o aktivaci aerosolu a její závislosti na meteorologických parametrech, především vertikální rychlosti proudění vzduchu a poloze v oblaku. Aktivovaná frakce byla vypočtena z rozdílu koncentrací naměřených za vtokem celého vzduchu a za vtokem PM2,5 . Obsah kapalné vody (LWC) byl vypočten z dohlednosti, poloha základny mraku byla odhadnuta z údajů ceilometru. Vertikální rychlost proudění vzduchu byla odhadnuta z radarového měření oblačnosti. Nebyla zjištěna žádná silná závislost mezi dohledností a vertikální rychlostí, což naznačuje, že oblačnost na stanici je většinou advekčního nebo inverzního původu. Viditelnost i LWC závisí na poloze v oblaku, přičemž nejvyšší hodnoty LWC byly zjištěny, když se stanice nacházela ve výšce 100 až 400 m nad základnou oblaku, nezávisle na skutečné hodnotě. Five in situ campaigns focused on aerosol-cloud interactions were conducted at Mount Milešovka in the Czech Republic to gain more insight into aerosol activation and its dependence on meteorological parameters, mainly vertical air velocity and position within the cloud. The activated fraction was calculated from the difference of concentrations measured behind the whole air inlet and the PM2.5 inlet. The liquid water content (LWC) was calculated from visibility, cloud base position was estimated from ceilometer data. Vertical air velocity was estimated from cloud radar. No strong dependence was found between visibility and vertical velocity, suggesting that the clouds at the station are mostly of advection or inversion origin. Both visibility and LWC depend on the position within the cloud, with the highest LWC values found when the station was between 100 and 400 m above the cloud base, independently of the actual value.
Keywords:
atmospheric aerosols; activation; cloud base
Available in a digital repository NRGL
(NE)ZÁVISLOST AKTIVACE AEROSOLU NA POZICI V OBLAKU
Na hoře Milešovka v České republice bylo provedeno pět in situ kampaní zaměřených na interakci aerosolu s oblakem, jejichž cílem bylo získat více informací o aktivaci aerosolu a její závislosti na ...
Influence of recreational activities on the distribution of forest wild boar rooting
Drimaj, J.; Balková, M.; Špoula, J.; Kamler, J.; Mikulka, O.; Plhal, R.; Homolka, Miloslav
2023 - English
The wild boar is a widely distributed and locally very numerous animal. The same is true in the conditions of Central Europe. Outside the growing season, it concentrates in forests, where it also actively searches for food sources. During this activity, it disturbs the soil surface, thereby significantly affecting the dynamics of the ecosystem. From an economic point of view, it limits the natural renewal of tree species, but from an ecological point of view, it changes habitat conditions and thus helps to increase biodiversity. Factors influencing the distribution of rooting across forest stands may be different. In this paper, we focused on the human factor and its influence on the rooting activity of wild boar in the Hodonínská Dúbrava, National natural monuments.
Keywords:
animal activity; disturbance; diversity; soil surface; wildlife
Fulltext is available at external website.
Influence of recreational activities on the distribution of forest wild boar rooting
The wild boar is a widely distributed and locally very numerous animal. The same is true in the conditions of Central Europe. Outside the growing season, it concentrates in forests, where it also ...
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