Number of found documents: 256
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Self-assembled structures in block copolymer blends
Holoubek, Jaroslav; Baldrian, Josef; Lal, J.
2005 - English
Phenomena associated with the order-disorder transition, microdomain morphology and phase behaviour of deuterated block copolymer mixture were studied by small-angle X-ray scattering and small-angle neutron scattering. Pomocí metod maloúhlového rozptylu rtg záření a maloúhlového rozptylu neutronů byly studovány jevy ODT, morfologie mikrodomén a fázové chování směsí deuterovaných blokových kopolymerů. Keywords: self-assembly; block copolymer blends; order-disorder transition Available at various institutes of the ASCR
Self-assembled structures in block copolymer blends

Phenomena associated with the order-disorder transition, microdomain morphology and phase behaviour of deuterated block copolymer mixture were studied by small-angle X-ray scattering and small-angle ...

Holoubek, Jaroslav; Baldrian, Josef; Lal, J.
Ústav makromolekulární chemie, 2005

Magnetic IDA-modified poly(glycidyl methacrylate) microspheres for IMAC phosphoprotein purification
Přikryl, P.; Horák, Daniel; Kučerová, Z.
2005 - English
Newly prepared magnetic iminodiacetic acid modified poly(glycidyl methacrylate) microspheres with immobilized FE III+ ions were used for separation of phosphorylated pepsins. Byly připraveny poly(glycidyl-methakrulátoré) mikročástice modifikované iminodioctovou kyselinou a využity k separaci fosforylovaných pepsinů. Keywords: proteinases; magnetic iminodiacetic acid; glycidyl methacrylate Available at various institutes of the ASCR
Magnetic IDA-modified poly(glycidyl methacrylate) microspheres for IMAC phosphoprotein purification

Newly prepared magnetic iminodiacetic acid modified poly(glycidyl methacrylate) microspheres with immobilized FE III+ ions were used for separation of phosphorylated pepsins....

Přikryl, P.; Horák, Daniel; Kučerová, Z.
Ústav makromolekulární chemie, 2005

Optical and electrical switching in organic semiconductors
Vala, M.; Weiter, M.; Nešpůrek, Stanislav; Zmeškal, O.
2005 - English
The work deals with tuning of electro-optical properties of polymeric media using reversible light-driven switching of photochromic spiropyran guest molecules. The significant change of dipole moment during the photochromic conversion allows construction of simple switching units. Optical responses of such devices were studied using absorbance and photoluminescence, electrical responses, were detected by impedance measurements. Práce se zabývá elektro-optickými vlastnostmi polymerních nosičů využívajících reversibilní světlem řízené spínání fotochromních aditiv typu spiropyranů. Změna dipólového momentu během fotochrmní konverse umožnila konstrukci jednoduché spínací jednotky. Optické odezvy byly studovány pomocí absorpce a fotoluminiscence, elektrické odezvy byly detekovány impedanční spektroskopií. Keywords: switch; poly(p-phenylenevinylene); spiropyrane Available at various institutes of the ASCR
Optical and electrical switching in organic semiconductors

The work deals with tuning of electro-optical properties of polymeric media using reversible light-driven switching of photochromic spiropyran guest molecules. The significant change of dipole moment ...

Vala, M.; Weiter, M.; Nešpůrek, Stanislav; Zmeškal, O.
Ústav makromolekulární chemie, 2005

Sensoric properties of soluble phthalocyanines
Severová, K.; Weiter, M.; Nešpůrek, Stanislav
2005 - English
Soluble phthalocyanine is suitable material for the preparation of humidity sensors. Thin films can be prepared from solution by casting or spin coating. Optical spectrum shows two main maxima located at 350 nm and 680 nm. Two additional weak bands with maxima located at 610 and 640 nm result from V vibrations and dimer formation, respectively. Rozpustný ftalocyanin je vhodným materiálem pro přípravu sensorů vlhkosti. Tenké filmy mohou být připraveny z roztoků odléváním nebo rotačním nanášením. Optické spektrum ukazuje 2 hlavní maxima nacházející se u 350 nm a 680 nm. Dva další slabé pásy u 610 a 640 nm vyplývají z V vibrací a z vytváření dimerů. Keywords: phthalocyanine; humidity sensor; electrical conductivity Available at various institutes of the ASCR
Sensoric properties of soluble phthalocyanines

Soluble phthalocyanine is suitable material for the preparation of humidity sensors. Thin films can be prepared from solution by casting or spin coating. Optical spectrum shows two main maxima located ...

Severová, K.; Weiter, M.; Nešpůrek, Stanislav
Ústav makromolekulární chemie, 2005

Programme and Abstract Booklet
Ilavský, Michal; Dušková, Miroslava
2005 - English
Proceedings of the 44th Microsymposium of Prague Meetings on Macromolecules contain abstracts of 42 lectures and over 100 posters that cover the areas of preparation and chemical modification of polymer gels and networks; gelation and network formation – experiment and theory; gel and network states of matter and gels in life sciences, technology and applications. Sborník 44. Mikrosymposia PMM obsahuje abstrakty 42 přednášek a více, než 100 posterů z oblastí: příprava a chemická modifikace polymerních sítí a gelů, gelace a tvorba sítí (experimentální a teoretická hlediska), gel a síť jako stav hmoty a gely v “life sciences”, technologii a aplikaci. Keywords: polymer gels; networks Available at various institutes of the ASCR
Programme and Abstract Booklet

Proceedings of the 44th Microsymposium of Prague Meetings on Macromolecules contain abstracts of 42 lectures and over 100 posters that cover the areas of preparation and chemical modification of ...

Ilavský, Michal; Dušková, Miroslava
Ústav makromolekulární chemie, 2005

Chemistry, Processing Structure, Properties and Applications of Nanostructured Polymers and Nanocomposites - Life-Cycle Engineering - Gender Issues - Programme and Abstracts
Dušek, Karel; Pfleger, Jiří
2005 - English
Abstrakta přednášek z NANOFUN-POLY Workshop on Chemistry, Processing Structure, Properties and Applications of Nanostructured Polymers and Nanocomposites - Life-Cycle Engineering - Gender Issues with international participation took place in Prague, in Keiserstein Palace. Abstracts of Lectures from NANOFUN-POLY Workshop on Chemistry, Processing Structure, Properties and Applications of Nanostructured Polymers and Nanocomposites - Life-Cycle Engineering - Gender Issues s mezinárodní účastí se konal v Keisersteinském paláci v Praze. Keywords: polymer structure; nanostructure; nanocomposites Available at various institutes of the ASCR
Chemistry, Processing Structure, Properties and Applications of Nanostructured Polymers and Nanocomposites - Life-Cycle Engineering - Gender Issues - Programme and Abstracts

Abstrakta přednášek z NANOFUN-POLY Workshop on Chemistry, Processing Structure, Properties and Applications of Nanostructured Polymers and Nanocomposites - Life-Cycle Engineering - Gender Issues with ...

Dušek, Karel; Pfleger, Jiří
Ústav makromolekulární chemie, 2005

Effects of .gamma.-irradiation on rheological properties of ultra-high molecular weight polyethylene melts
Mikešová, Jana; Nevoralová, Martina
2005 - English
Ultra-high molecular weight polyethylene is widely used as material in orthopaedic implants. Melt rheology was used to evaluate the result of simultaneous crosslinking and chain scission process in the polymer, .gamma.-irradiated in the solid state. The predominant mechanism in the process was strongly influenced by irradiation dose and dose-rate. An important result was obtained for the polymer irradiated with the sterilization dose 25 kGy and stored in nitrogen when no significant degradation of the polymer was observed. Klinické problémy pacientů způsobené částicemi ultravysokomolekulárního polyethylenu uvolněnými do organismu z kloubních implantátů, vyvolaly zájem o radiační síťování tohoto polymeru. V polymeru po ozáření dochází jak k síťování tak i degradaci. Převahu jednoho z procesů je možné pozorovat meřením reologických vlastností taveniny polymeru. Testovány byly vlivy různých dávek záření a rychhostí ozařování. Důležitým závěrem práce bylo zjištění, že v polymeru ozářeném sterilizační dávkou 25 kGy a uchovávaném v dusíkové atmosféře nebyla pozorována degradace. Keywords: rheology; UHMWPE Available at various institutes of the ASCR
Effects of .gamma.-irradiation on rheological properties of ultra-high molecular weight polyethylene melts

Ultra-high molecular weight polyethylene is widely used as material in orthopaedic implants. Melt rheology was used to evaluate the result of simultaneous crosslinking and chain scission process in ...

Mikešová, Jana; Nevoralová, Martina
Ústav makromolekulární chemie, 2005

Hydrophilic polymer systems in capillary electrophoretic separations
Guryča, Vilém; Novotný, M. V.; Michálek, Jiří; Pacáková, V.
2005 - English
The present work deals with preparations of polymeric stationary phases/coatings for separations of biologically active compounds such as glycoproteins and glycans. Práce pojednává o přípravě polymerních stacionárních fázích/filmech, které slouží pro kapilárně elektroforetické separace biologicky aktivních sloučenin, jako např. glykoproteinů nebo glykanů. Keywords: analytical glycobiology; capillary electrochromatography; hydrophilic acrylamide monoliths Available at various institutes of the ASCR
Hydrophilic polymer systems in capillary electrophoretic separations

The present work deals with preparations of polymeric stationary phases/coatings for separations of biologically active compounds such as glycoproteins and glycans....

Guryča, Vilém; Novotný, M. V.; Michálek, Jiří; Pacáková, V.
Ústav makromolekulární chemie, 2005

Preparation and characterization of molecularly imprinted monolithic columns
Širc, Jakub; Bosáková, Z.; Michálek, Jiří; Guryča, Vilém
2005 - English
By in situ polymerization prepared molecularly imprinted polymer rods were characterized by porosimetry, scanning electron microscopy and by separation of standard hydrophobic solutes and enantiomer pairs. Byly připraveny monolitické kolony na principu vtištěných polymerů a charakterizovány pomocí rtuťové porozimetrie, skenovací elektronové mikroskopie. Jejich separační vlastnosti byly sledovány na dělení směsi hydrofobních standardů a optických izomerů. Keywords: molecular imprinting; in situ polymerization; chiral separation Available at various institutes of the ASCR
Preparation and characterization of molecularly imprinted monolithic columns

By in situ polymerization prepared molecularly imprinted polymer rods were characterized by porosimetry, scanning electron microscopy and by separation of standard hydrophobic solutes and enantiomer ...

Širc, Jakub; Bosáková, Z.; Michálek, Jiří; Guryča, Vilém
Ústav makromolekulární chemie, 2005

Modification of isotactic polypropylene
Ličko, M.; Jeníková, Z.; Rybníček, J.; Horník, J.; Steidl, J.; Raab, Miroslav
2005 - English
Injection moulded samples of polypropylene were used to study the effect of trigonal .beta.-phase and ethylene propylene rubber on mechanical-physical properties in respect to microstructure. The results were compared with pure isotactic polypropylene, .beta.phase induced by 0.33 weight percent of a nucleation reagent and 20 weight percent of EPM rubber increases the toughness of iPP. A substantial increase in toughness was observed by combining both additives resulting in spherolite refinement and reduction in amorphous content. However, the improvement in toughness was at the expense of the yield strength and modulus of elasticity. Vliv trigonální .beta.-fáze izotaktického polypropylenu na mikrostrukturu a mechanicko-fyzikální vlastnosti byl sledován u zkušebních vzorků připravených technologií vstřikování. Keywords: isotactic polypropylene Available at various institutes of the ASCR
Modification of isotactic polypropylene

Injection moulded samples of polypropylene were used to study the effect of trigonal .beta.-phase and ethylene propylene rubber on mechanical-physical properties in respect to microstructure. The ...

Ličko, M.; Jeníková, Z.; Rybníček, J.; Horník, J.; Steidl, J.; Raab, Miroslav
Ústav makromolekulární chemie, 2005

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