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Electrochemical Valorization of Lignocellulosic Biomass Amination of Furfural and 5-Hydroxymethylfurfural
Donkeng Dazie, Joel; Koláčná, Lucie; Urban, Jiří; Lamač, Martin; Ludvík, Jiří
2024 - English
Furfural (FF) and 5-hydroxymethylfurfural (HMF) isolated from waste lignocellulosic biomass represent renewable sources. The present contribution deals with the transformation of FF and HMF into furfuryl amines which are important precursors namely for pharmaceutical synthesis. First, FF and HMF underwent condensation reactions with various amines which were electrochemically monitored to optimize the process. The resulting Schiff bases were identified by NMR and subsequently electrochemically reduced in basic media. The vicinal diamine (aminopinacol) was the main product besides the expected furfuryl amines. This reaction is a contribution to green synthesis because it was performed electrochemically, in water, and without any metallic catalysts.
Keywords:
furfural; 5-hydroxymethylfurfural; (di)amines
Available on request at various institutes of the ASCR
Electrochemical Valorization of Lignocellulosic Biomass Amination of Furfural and 5-Hydroxymethylfurfural
Furfural (FF) and 5-hydroxymethylfurfural (HMF) isolated from waste lignocellulosic biomass represent renewable sources. The present contribution deals with the transformation of FF and HMF into ...
Electrochemical Properties of Newly Synthesized Selaginpulvilins
Dostálová, L.; Sokolová, Romana; Schwarzová-Pecková, K.; Rýček, L.
2024 - English
The electrochemical properties of newly synthesized selaginpulvilin were investigated by cyclic voltammetry and UV-Vis spectroelectrochemistry. The subject of the study were two\nselaginpulvilins differing in the presence of a hydroxyl group in the media of 0.1 mol L-1 tetrabutylammonium hexafluorophosphate as supporting electrolyte in anhydrous acetonitrile. Both\ncompounds provided an oxidative signal in the positive region until +2.0 V.
Keywords:
oxidation; cyclic voltammetry; selaginpulvilins
Available on request at various institutes of the ASCR
Electrochemical Properties of Newly Synthesized Selaginpulvilins
The electrochemical properties of newly synthesized selaginpulvilin were investigated by cyclic voltammetry and UV-Vis spectroelectrochemistry. The subject of the study were two\nselaginpulvilins ...
3D-printed Electrodes with Nearly Ideal Charge Transfer Characteristics
Vaněčková, Eva; Sebechlebská, Táňa; Kolivoška, Viliam
2024 - English
3D printing is an outstanding manufacturing tool for prototyping customized designs at reduced time and costs, having found applications in fields such as medicine or the automotive industry. The development of printable electrically conductive composite materials brought a revolution to electrochemistry, with 3D-printed electrodes being intensively studied from the viewpoint of\nanalytical performance and stability. However, it is often reported that 3D-printed electrodes have poor charge transfer characteristics, typically due to limited exposure of the electrically conductive phase at the composite surface to the surrounding solution. In this work, we devise and apply simple electrochemical activation procedures that lead to a significant improvement of charge transfer characteristics of 3D printed electrodes.
Keywords:
three-dimensional printing; electrochemistry; electrodes
Available on request at various institutes of the ASCR
3D-printed Electrodes with Nearly Ideal Charge Transfer Characteristics
3D printing is an outstanding manufacturing tool for prototyping customized designs at reduced time and costs, having found applications in fields such as medicine or the automotive industry. The ...
Book of Abstracts. 19th Youth symposium on experimental solid mechanics
Kytýř, Daniel; Zlámal, Petr; Pagliaro, A.; Doktor, T.
2024 - English
The YSESM symposium provides a forum for young researchers and engineers, PhD students and students dealing with subjects of experimental mechanics. The Symposium concentrates on current work in all areas of experimental research and its application in solid and fluid mechanics. The topic will particularly concern to: Conventional and advanced experimental methods in solid and fluid mechanics - Non-destructive testing and inspection - Measurements in material science - Computer assisted testing and simulation - Engineering design simulation - Hybrid methods, experimental techniques – Numerical simulation - Optical methods and image processing - Measurements in biomechanics - Sensor techniques for micro- and nano-applications - Measurement methods for forensic engineering
Keywords:
experimental mechanics; solid mechanics; fluid mechanics
Available at various institutes of the ASCR
Book of Abstracts. 19th Youth symposium on experimental solid mechanics
The YSESM symposium provides a forum for young researchers and engineers, PhD students and students dealing with subjects of experimental mechanics. The Symposium concentrates on current work in all ...
Numerical study of the steady airflow in the human respiratory system during inhaling and exhaling
Lancmanová, Anna; Bodnár, Tomáš
2024 - English
This paper presents some of the initial results of the numerical simulations of a steady turbulent flow in human upper airways during inhalation and exhalation. The mathematical model is based on the system of Reynolds-Averaged incompressible Navier-Stokes equations complemented by the SST k − ω turbulence model. The simulations were performed using finite-volume open source solver OpenFOAM on a realistic three-dimensional geometry. The main aim of this particular study is to verify the computational setup with special focus on appropriate choice and implementation of boundary conditions. The prescribed boundary conditions are chosen to mimic the physiological conditions during normal breathing cycle. This study aims to gain an insight into the airflow behavior during the inhalation and exhalation process by comparing the results of two distinct simulations corresponding to two different (opposite) flow rates . The obtained local flow rates and flow fields for both cases are presented and mutually compared. This initial work should serve as a foundation for future more complex simulations that will include the time-dependent and compressible effects.
Keywords:
human airways; incompressible Navier-Stokes; OpenFOAM
Available in digital repository of the ASCR
Numerical study of the steady airflow in the human respiratory system during inhaling and exhaling
This paper presents some of the initial results of the numerical simulations of a steady turbulent flow in human upper airways during inhalation and exhalation. The mathematical model is based on the ...
Verification of the dynamic properties of a new model turbine wheel with free blades
Voronova, Evgeniya; Procházka, Pavel; Maturkanič, Dušan; Mekhalfia, Mohammed Lamine; Hodboď, Robert
2024 - English
The paper describes a new experimental model of turbine wheel with free blades. Verification tests were carried out using a Doppler laser vibrometer, with a focus on the equipment parameters under various conditions. The measurements were performed in the Laboratory of Rotational Laser Vibrometry originated at the Institute of Thermomechanics AS CR, v.v.i.
Keywords:
natural frequencies; vibration; blade; laser; turbine
Available at various institutes of the ASCR
Verification of the dynamic properties of a new model turbine wheel with free blades
The paper describes a new experimental model of turbine wheel with free blades. Verification tests were carried out using a Doppler laser vibrometer, with a focus on the equipment parameters under ...
Matching to suppliers in the production network: an empirical framework
Alfaro-Ureña, A.; Zacchia, Paolo
2024 - English
This paper develops a framework for the empirical analysis of the determinants of input supplier choice on the extensive margin using firm-to-firm transaction data. Building on a theoretical model of production network formation, we characterize the assumptions that enable a transformation of the multinomial logit likelihood function from which the seller fixed effects, which encode the seller marginal costs, vanish. This transformation conditions, for each subnetwork restricted to one supplier industry, on the out-degree of sellers (a sufficient statistic for the seller fixed effect) and the in-degree of buyers (which is pinned down by technology and by “make-or-buy” decisions). This approach delivers a consistent estimator for the effect of dyadic explanatory variables, which in our model are interpreted as matching frictions, on the supplier choice probability. The estimator is easy to implement and in Monte Carlo simulations it outperforms alternatives based on group fixed effects. In an empirical application about the effect of a major Costa Rican infrastructural project on firm-to-firm connections, our approach yields estimates typically much smaller in magnitude than those from naive multinomial logit.
Keywords:
production network; supplier choice; conditional logit
Fulltext is available at external website.
Matching to suppliers in the production network: an empirical framework
This paper develops a framework for the empirical analysis of the determinants of input supplier choice on the extensive margin using firm-to-firm transaction data. Building on a theoretical model of ...
Disappearing stepping stones: technological change and career paths
Kashkarov, Daniil; Artemev, V.
2024 - English
Which career paths lead workers towards high-skilled non-routine cognitive occupations? Using PSID data, we show that, for a significant share of workers, a career path towards non-routine cognitive occupations goes through middle-skilled routine occupations, with the majority going through a subset of routine cognitive occupations. We then argue that the decline in employment in routine cognitive occupations due to routine-biased technological change can negatively affect the chances of younger cohorts joining high-skilled occupations. To test this hypothesis, we develop a structural occupational choice model that endogenously generates realistic career paths and estimate it using PSID data and job ad data from three major US outlets covering the period from 1940 to 2000. Our estimations suggest that, on average, 6% of workers ending up in non-routine cognitive occupations use routine cognitive occupations as stepping stones that allow them to maintain and accumulate human capital and experience relevant for later employment in high-skilled occupations. A fall in employment opportunities in routine cognitive occupations over the period of the most intensive routine-biased technological change led to at least 1.37 million lost high-skilled workers who got stuck in less skilled occupations.
Keywords:
routine-biased technological change; occupational choice; human capital
Fulltext is available at external website.
Disappearing stepping stones: technological change and career paths
Which career paths lead workers towards high-skilled non-routine cognitive occupations? Using PSID data, we show that, for a significant share of workers, a career path towards non-routine cognitive ...
Reaction Mechanisms of Psychoactive Compounds
Sokolová, Romana; Beneš, Marek; Jiroušková, Eliška; Degano, I.
2024 - English
The reaction mechanism of selected new psychoactive substances (NPS) 4-methylpentedrone and 2-(((4-ethyl-2,5-dimethoxyphenethyl)amino)methyl)phenol was investigated based on their\nelectrochemical and spectroelectrochemical properties. Both drugs were examined by means of cyclic voltammetry using diagnostic parameters for particular reaction schemes, UV/Vis, and IR\nspectroelectrochemistry. Since water participates in the redox mechanism of both studied compounds, the reaction mechanism was studied under a controlled amount of water in an\nacetonitrile environment.
Keywords:
oxidation; reduction; IR spectrochemistry
Available on request at various institutes of the ASCR
Reaction Mechanisms of Psychoactive Compounds
The reaction mechanism of selected new psychoactive substances (NPS) 4-methylpentedrone and 2-(((4-ethyl-2,5-dimethoxyphenethyl)amino)methyl)phenol was investigated based on their\nelectrochemical and ...
Spectroelectrochemical Devices for Monitoring of Intermediates and Products on Carbonbased Composite Electrodes
Vaněčková, Eva; Šikula, M.; Hrdlička, Vojtěch; Sebechlebská, Táňa; Kolivoška, Viliam
2024 - English
Spectroelectrochemistry (SEC), as an interdisciplinary field, provides us with more comprehensive information about electroactive molecules involved in charge transfer reactions. Commercially\navailable SEC cells most often have an incorporated platinum working electrode, which can limit the range of the usable potential window and, in addition, can complicate the analysis due to the\nabsorption phenomenon. In this work, we designed and manufactured two types of custom-made SEC cells employing optically transparent carbon-based working electrodes for UV-Vis monitoring of reactants and electrogenerated intermediates and products. The first SEC cell is entirely manufactured by 3D printing using fused deposition modeling (FDM) by combining optically transparent (PET) and electrically conductive (PLA-CB) filaments. The second SEC cell employs pencil graphite (PG) rods as the working electrode (PGE) and its body is manually assembled from quartz slides. The functionality of the FDM 3D printed SEC cell and manually assembled quartz SEC cell were verified by cyclic voltammetry with in situ UV-Vis spectroscopic absorption monitoring of ruthenium(III) acetylacetonate (Ru(ac)3) redox-active probe dissolved in an aqueous or non-aqueous deaerated solvent, respectively. Both presented cells enable complete redox reversible conversion and strictly oxygen-free conditions.
Keywords:
pencil graphite electrode; spectroelectrochemistry; 3D printed electrode
Available on request at various institutes of the ASCR
Spectroelectrochemical Devices for Monitoring of Intermediates and Products on Carbonbased Composite Electrodes
Spectroelectrochemistry (SEC), as an interdisciplinary field, provides us with more comprehensive information about electroactive molecules involved in charge transfer reactions. ...
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