No (5612)
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Structural analysis of polysaccharides from mushroom hericium Erinaceus mftccb 134
Bleha, R.; Čopíková, J.; Sushytskyi, Leonid; Vannucci, Luca; Sinica, A.; Jozífek, M.; Jablonský, I.; Klouček, P.
2023 - English
The aim of this research was the structural characterisation of polysaccharides isolated from fruiting bodies of the cultivating medicinal mushroom Hericium erinaceus MFTCCB 134. Cold and hot water extracts (CWE, HWE) were obtained and purified, and followed by alkali extraction from the reminder solids. The composition and structure of the fractions were analysed by FTIR spectroscopy, and neutral sugars/linkage analyses were determined by GC/FID and GC/MS, respectively. Galactose, fucose and glucose were found in purified CWE,\nwhile glucose predominated in purified HWE.
Keywords:
Hericium erinaceus; polysaccharides; mushrooms
Available at various institutes of the ASCR
Structural analysis of polysaccharides from mushroom hericium Erinaceus mftccb 134
The aim of this research was the structural characterisation of polysaccharides isolated from fruiting bodies of the cultivating medicinal mushroom Hericium erinaceus MFTCCB 134. Cold and hot water ...
Where does the water in Plešné lake come from?
Kopáček, Jiří; Porcal, Petr
2023 - Czech
Application of three approaches to estimate the contribution of groundwater in the water balance of Plešné Lake. Aplikace tří metod k odhadu podílu podzemní vody ve vodní bilanci Plešného jezera.
Keywords:
lake; groundwater contribution; isotopes
Available at various institutes of the ASCR
Where does the water in Plešné lake come from?
Application of three approaches to estimate the contribution of groundwater in the water balance of Plešné Lake.
Analytical Derivatization for Identification of Electrochemical Oxidation Products of Fentanyls
Barták, P.; Skopalová, J.; Jerga, R.; Štolbová, D.; Navrátil, Tomáš; Langmaier, Jan
2023 - Czech
Analytical derivatization and GC-MS analysis were employed for the identification of main\nproducts from the electrochemical oxidation of fentanyl derivatives. Chemical derivatization\nprovides proof of the chemical reactivity of functional groups in oxidation products and serves\nfor the chemical conversion of target compounds into the second series of derivatives to confirm\nthe identification of particular products. Using the direct GC-MS analysis of oxidation products,\nderivatization of aldehydes with cysteamine and derivatization of amides by acidic hydrolysis\nand subsequent reaction with ethylchloroformiate, phenylacetaldehyde, and Nphenylpropanamide\nwere unambigously identified as oxidation products from fentanyl,\nthiophen-2-ylacetaldehyde, and N-phenylpropanamide from sufentanil, and\nphenylacetaldehyde and 2-furanilid from furanylfentanyl. Analytická derivatizace a plynová chromatografie s hmotnostní spektrometrií se osvědčily jako\nvhodné nástroje pro identifikaci oxidačních produktů a řešení reakčního mechanismu\nelektrochemické oxidace fentanylů a dalších opioidů. Provedené experimenty potvrdily\npřítomnost fenylacetaldehydu a N-fenylpropanamidu v roztoku po elektrochemické oxidaci\nfentanylu. V případě sufentanilu byl jako odpovídající aldehydický produkt prokázán thiofen-\n2-ylacetaldehyd a v případě furanylfentanylu byl jako amidický produkt prokázán zcela\nanalogicky 2-furanilid.
Keywords:
electrochemical oxidation; fentanyl; sufentanil; furanylfentanyl
Available on request at various institutes of the ASCR
Analytical Derivatization for Identification of Electrochemical Oxidation Products of Fentanyls
Analytical derivatization and GC-MS analysis were employed for the identification of main\nproducts from the electrochemical oxidation of fentanyl derivatives. Chemical derivatization\nprovides proof ...
Speciation analysis employing hydride generation
Matoušek, Tomáš
2023 - Czech
The lecture presented employing of different ways of hydride generation- selective generation, postcolumn generation and cryotrapping- useful of element speciation analysis. Examples from our laboratory covered applications from the field of clinical, food and natural water analysis. Přednáška prezentovala různé způsoby využití postupu generování hydridů- selektivní generování, postkolonové generování a generování s kryoseparací- v prvkových speciačních analýzách. Příklady z naší laboratoře zahrnovaly aplikace z oblasti klinické analýzy, analýzy potravin a přírodních vod.
Keywords:
hydrides generation; inductively coupled plasma mass spectrometry; speciation analysis
Available on request at various institutes of the ASCR
Speciation analysis employing hydride generation
The lecture presented employing of different ways of hydride generation- selective generation, postcolumn generation and cryotrapping- useful of element speciation analysis. Examples from our ...
Volatile species generation – an efficient sample introduction technique for ICP-MS
Musil, Stanislav
2023 - Czech
Various techniques of volatile species generation, the ways of coupling to ICP-MS and recent results of our laboratory in the field of photochemical vapor generation of transition metals were presented in this lecture. V rámci této přednášky byly prezentovány různé techniky generování těkavých sloučenin (specií), možnosti spojení s ICP-MS a nedávné výsledky naší laboratoře v oblasti fotochemického generování těkavých specií přechodných prvků.
Keywords:
volatile species generation; inductively coupled plasma mass spectrometry; photochemical vapor generation
Available at various institutes of the ASCR
Volatile species generation – an efficient sample introduction technique for ICP-MS
Various techniques of volatile species generation, the ways of coupling to ICP-MS and recent results of our laboratory in the field of photochemical vapor generation of transition metals were ...
3D Printed Microfluidic Cell for Spectroelectrochemical Analysis
Šikula, M.; Vaněčková, Eva; Hromadová, Magdaléna; Kolivoška, Viliam
2023 - English
Recent advances in fused deposition modeling 3D printing (FDM 3DP) enabled \nthe manufacture of customized spectroelectrochemical (SEC) devices. Despite significant progress, \nreported designs still rely on conventional optical components (windows and cuvettes). In this \nwork, we apply bi-material FDM 3DP combining electrically conductive and optically \ntranslucent filaments to manufacture a fully integrated microfluidic SEC device. Employing cyclic \nvoltammetric measurements with redox probes, we demonstrate that the platform allows SEC sensing of \nreactants, intermediates, and products of charge transfer reactions in an oxygen- free \nenvironment. Developed approaches pave the way for SEC d vices with dramatically\nreduced costs compared to currently available commercial platforms.\n
Keywords:
spectroelectrochemistry; three-dimensional printing; fused deposition modeling
Available on request at various institutes of the ASCR
3D Printed Microfluidic Cell for Spectroelectrochemical Analysis
Recent advances in fused deposition modeling 3D printing (FDM 3DP) enabled \nthe manufacture of customized spectroelectrochemical (SEC) devices. Despite significant progress, ...
Electrochemical Properties of Mixed Self-Assembled Monolayers Based on Terpyridine Transition Metal Complexes
Kocábová, Jana; Nováková Lachmanová, Štěpánka; Vavrek, František; Valášek, M.; Hromadová, Magdaléna
2023 - English
This work presents the electrochemical characterization of mixed self-assembled monolayers\n(SAMs) of [Os(terpy)2]2+ and terpyridine connected by tripodal anchoring groups to the\npolycrystalline gold bead electrode and provides a comparison with SAM based on\n[Os(terpy)2]2+ tripodal molecules without diluting terpyridine tripodal molecules. It is shown\nthat both arrangements enable reproducible preparation of well-defined compact films. The\nelectron transfer rate constant for mixed SAM was determined from cyclic voltammograms\naccording to Laviron’s analysis and compared with the rate constant obtained previously for\nSAM containing only [Os(terpy)2]2+ tripod.
Keywords:
transition metal complexes; terpyridine; tripodal anchor
Available on request at various institutes of the ASCR
Electrochemical Properties of Mixed Self-Assembled Monolayers Based on Terpyridine Transition Metal Complexes
This work presents the electrochemical characterization of mixed self-assembled monolayers\n(SAMs) of [Os(terpy)2]2+ and terpyridine connected by tripodal anchoring groups to the\npolycrystalline gold ...
Elimination Voltammetry with Linear Scan: Advantages and Disadvantages
Navrátil, Tomáš; Trnková, L.; Hrdlička, Vojtěch; Li, X.
2023 - English
Elimination voltammetry with linear scan (EVLS) represents an almost traditional\nmathematical method that helps to obtain additional and detailed information about the recorded\nelectrochemical signals and therefore, to better understand the analyzed systems. Although it\nhas been substantially developed and expanded during its existence of more than a quarter of a\ncentury and has found many areas of application, like any other mathematical and experimental\nmethod, it exhibits several advantages and disadvantages. In this contribution, we summarize\nits strengths, weaknesses, opportunities, as well as threats.\n
Keywords:
elimination voltammetry with linear scan; advantages; disadvantages
Available on request at various institutes of the ASCR
Elimination Voltammetry with Linear Scan: Advantages and Disadvantages
Elimination voltammetry with linear scan (EVLS) represents an almost traditional\nmathematical method that helps to obtain additional and detailed information about the recorded\nelectrochemical ...
EI spectra interpretation
Polášek, Miroslav
2023 - Czech
Introduction to the interpretation of mass spectra. Basic mechanisms of fragmentation reactions in electron ionization. An intensive exercise on selected examples of mass spectra of electron ionization of different classes of organic compounds, which will be carried out in the spirit of the elementary didactic principle of progression from simple to complex with maximum emphasis on the independent work of the participants.\n\n Úvod do problematiky interpretace hmotnostních spekter. Základní mechanizmy fragmentačních reakcí při elektronové ionizaci. Intenzivní cvičení na vybraných příkladech hmotnostních spekter elektronové ionizace různých tříd organických sloučenin, které bude probíhat v duchu elementární didaktické zásady postupu od jednoduchého ke složitějšímu s maximálním důrazem na samostatnou práci účastníků.
Keywords:
mass spectrometry; EI; data analysis
Available at various institutes of the ASCR
EI spectra interpretation
Introduction to the interpretation of mass spectra. Basic mechanisms of fragmentation reactions in electron ionization. An intensive exercise on selected examples of mass spectra of electron ...
Forecast model of DOC in the inflow to the Římov water reservoir and in the withdrawal of water from the reservoir.
Hejzlar, Josef; Porcal, Petr; Kopáček, Jiří; Jarošík, Jiří; Paule-Mercado, Ma
2023 - Czech
Long-term and seasonal changes in dissolved organic carbon (DOC) concentration and their causes in the years 1969–2021 were evaluated for the main tributary to the Římov water supply reservoir. Pro hlavní přítok do vodárenské nádrže Římov byly vyhodnoceny dlouhodobé a sezónní změny koncentrace rozpuštěného organického uhlíku (DOC) a jejich příčiny v letech 1969–2021.
Keywords:
water; dissolved organic matter; reservoir
Available at various institutes of the ASCR
Forecast model of DOC in the inflow to the Římov water reservoir and in the withdrawal of water from the reservoir.
Long-term and seasonal changes in dissolved organic carbon (DOC) concentration and their causes in the years 1969–2021 were evaluated for the main tributary to the Římov water supply reservoir.
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