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N-alkylation of a lysergic acid derivative under PTC conditions in a continuous arrangement using sonication
Jaklová, Natalie
2023 - anglický
This contribution focuses on the application of sonication to the synthesis of a methyl ester of the 1-methyl-10α-methoxydihydrolysergic acid (MeLUME).
Klíčová slova:
sonication; synthesis; methyl ester
Plné texty jsou dostupné v digitálním repozitáři NUŠL
N-alkylation of a lysergic acid derivative under PTC conditions in a continuous arrangement using sonication
This contribution focuses on the application of sonication to the synthesis of a methyl ester of the 1-methyl-10α-methoxydihydrolysergic acid (MeLUME).
PROCESSING OF THE DATA MEASURED WITH CLOUD CONDENSATION NUCLEI COUNTER IN YEAR 2020 FOR SUBMISSION TO EBAS DATABASE
Moravec, Pavel; Jindra, Tomáš; Wagner, Zdeněk; Ždímal, Vladimír
2023 - anglický
Aerosol particles in the atmosphere that allow water vapor to condense and form cloud droplets are called Cloud Condensation Nuclei (CCN). Elevated concentrations of CCN tend to increase the concentration and decrease the size of cloud droplets. This can lead to suppression of precipitation in shallow and short-lived clouds and to greater convective overturning and more precipitation in deep convective clouds, Rose et al.(2010). The response of cloud properties and precipitation processes to increasing anthropogenic aerosol concentrations represents one of the largest uncertainties in the current understanding of climate change. One of the fundamental challenges is to determine the ability of aerosol particles to act as CCN under relevant atmospheric conditions. Knowledge of the spatial and temporal distribution in the atmosphere is essential to incorporate the effects of CCN into meteorological models of all scales, Huang et al. (2007). Long-term CCN measurements are performed at aerosol monitoring sites such as those forming ACTRIS (Aerosols, Clouds, and Trace Gases Research Infrastructure) network. Measured data are then submitted to the EBAS database, where they are available for the other ACTRIS researchers. In this paper, we present our experience with the processing of the data measured with CCNC for submission to the EBAS database. The data prepared for submission to EBAS from year 2020 are also presented.
Klíčová slova:
atmospheric aerosols; CCNC; cloud condensation nuclei concentrations
Plné texty jsou dostupné v digitálním repozitáři NUŠL
PROCESSING OF THE DATA MEASURED WITH CLOUD CONDENSATION NUCLEI COUNTER IN YEAR 2020 FOR SUBMISSION TO EBAS DATABASE
Aerosol particles in the atmosphere that allow water vapor to condense and form cloud droplets are called Cloud Condensation Nuclei (CCN). Elevated concentrations of CCN tend to increase the ...
DRONE-BASED VERTICAL MEASUREMENTS OF BLACK CARBON AEROSOLS AT A RURAL BACKGROUND AND AN URBAN SITE
Julaha, Kajal; Zíková, Naděžda; Ždímal, Vladimír
2023 - anglický
Black Carbon (BC) aerosols are primary particles emitted into the atmosphere as a by-product of incomplete combustion processes. BC absorbs solar radiation and altersthe radiation budget of the Earth(Bond et al., 2013). The radiative properties of BC heavily depend on its vertical profiles(Haywood and Ramaswamy, 1998). For example, BC in the free troposphere can enhance its radiative forcing by trapping energy emitted from lower cloud layers. \nThe modeling-based studies on BC vertical distribution are particularly poor (Chen et al., 2022), creating a need to measure the vertical distribution of BC on a regional scale,from areas characterized by anthropogenic emissions from the ground to those characterized by long-range transport(Ramana et al., 2010). Among all the other methods, drones have recently gained popularity because of their high-cost efficiency, flexibility, and mobility. Besides comparing BC aerosol vertical distribution at an urban and a regional background site, this study also calibrates drone measurements using a 230-meter tower.
Klíčová slova:
vertical profile; drone; rural background
Plné texty jsou dostupné v digitálním repozitáři NUŠL
DRONE-BASED VERTICAL MEASUREMENTS OF BLACK CARBON AEROSOLS AT A RURAL BACKGROUND AND AN URBAN SITE
Black Carbon (BC) aerosols are primary particles emitted into the atmosphere as a by-product of incomplete combustion processes. BC absorbs solar radiation and altersthe radiation budget of the ...
An Enzymatic Biosensor with Amperometric Detection in a Flow Injection Analysis for the Determination of L-lactic Acid: Development and Application
Tvorynska, Sofiia; Barek, J.; Josypčuk, Bohdan
2023 - anglický
An amperometric biosensor consisting of an enzymatic mini-reactor (lactate oxidase covalently\nattached to −NH2 functionalized mesoporous silica powder SBA−15 using glutaraldehyde) and\na silver amalgam-based screen-printed electrode acting as a transducer was developed for the\ndetermination of L-lactic acid (LA) in FIA. The detection potential of −0.9 V vs. Ag pseudoreference\nelectrode was applied for cathodic detection of enzymatically consumed oxygen.\nUnder the optimized conditions, the constructed biosensor enabled selective determination of\nLA with a micromolar limit of detection. Importantly, the proposed biosensor represented\nexcellent operational stability after ≥350 measurements. Finally, it was successfully applied to\nreal sample analysis.
Klíčová slova:
L-lactic acid; Lactate oxidase; Amperometric biosensor; silver amalgam
Plné texty jsou dostupné na vyžádání prostřednictvím repozitáře Akademie věd.
An Enzymatic Biosensor with Amperometric Detection in a Flow Injection Analysis for the Determination of L-lactic Acid: Development and Application
An amperometric biosensor consisting of an enzymatic mini-reactor (lactate oxidase covalently\nattached to −NH2 functionalized mesoporous silica powder SBA−15 using glutaraldehyde) and\na silver ...
Simultaneous online determination of nitric acid and nitrates in ambient air
Alexa, Lukáš; Čmelíková, D.; Cigánková, Hana; Mikuška, Pavel
2023 - anglický
The innovated method for the simultaneous online determination of HNO3/NO3- in ambient air was developed. Due to high sensitivity of CLD (LOD = 5.1 nM in water solution, 3 s/n) no preconcentration method is required. The online methods were compared with the results obtained with the offline method based on sampling using filters and dry denuders (DD) covered by 0.5% NaF with subsequent analysis by ion chromatography (model ICS-2100, Dionex, USA) and capillary electrophoresis (model Agilent 7100, Agilent Technologies, USA).
Klíčová slova:
nitric acid; nitrates; online analysis; CGU-ACTJU; CWEDD
Plné texty jsou dostupné v digitálním repozitáři Akademie Věd.
Simultaneous online determination of nitric acid and nitrates in ambient air
The innovated method for the simultaneous online determination of HNO3/NO3- in ambient air was developed. Due to high sensitivity of CLD (LOD = 5.1 nM in water solution, 3 s/n) no preconcentration ...
Přehled účinků vybraných doplňků stravy na prevenci a léčbu kardiovaskulárních onemocnění
Šíma, Petr; Michalová, I.
2023 - český
Sdělení je přehledem vybraných studií, které se zabývaly účinky dlouhodobějšího podávání některých doplňků stravy,\no nichž se předpokládá, že pozitivně ovlivňují prevenci a léčbu nejzávažnějších nesdělných (chronických) onemocnění, což jsou\nv současné době především onemocnění kardiovaskulární. Jenom u nás jsou srdeční onemocnění už dlouhodobě příčinou smrti\ntéměř dvou třetin lidí.\nCílem tohoto sdělení bylo ukázat, že navzdory popularitě a masovému rozšíření doplňků stravy jsou jejich zdravotní přínosy\nsporné. The article is an overview of selected studies that dealt with the effects of long-term administration of certain dietary supplements,\nwhich are assumed to positively influence the prevention and treatment of the most serious non-communicable (chronic) diseases, which are currently mainly cardiovascular disease. Only in our country, heart diseases have been the cause of death for a long time\nalmost two-thirds of people. \nThe aim of this study was to show that despite the popularity and mass distribution of dietary supplements, their health benefits are questionable.\n
Klíčová slova:
dietary supplements; cardiovascular diseases; antioxidants
Dokument je dostupný na externích webových stránkách.
Přehled účinků vybraných doplňků stravy na prevenci a léčbu kardiovaskulárních onemocnění
Sdělení je přehledem vybraných studií, které se zabývaly účinky dlouhodobějšího podávání některých doplňků stravy,\no nichž se předpokládá, že pozitivně ovlivňují prevenci a léčbu nejzávažnějších ...
Odkud pochází voda v Plešném jezeře?
Kopáček, Jiří; Porcal, Petr
2023 - český
Aplikace tří metod k odhadu podílu podzemní vody ve vodní bilanci Plešného jezera. Application of three approaches to estimate the contribution of groundwater in the water balance of Plešné Lake.
Klíčová slova:
lake; groundwater contribution; isotopes
Plné texty jsou dostupné na jednotlivých ústavech Akademie věd ČR.
Odkud pochází voda v Plešném jezeře?
Aplikace tří metod k odhadu podílu podzemní vody ve vodní bilanci Plešného jezera.
Application of three approaches to estimate the contribution of groundwater in the water balance of Plešné Lake.
Structural analysis of polysaccharides from mushroom hericium Erinaceus mftccb 134
Bleha, R.; Čopíková, J.; Sushytskyi, Leonid; Vannucci, Luca; Sinica, A.; Jozífek, M.; Jablonský, I.; Klouček, P.
2023 - anglický
The aim of this research was the structural characterisation of polysaccharides isolated from fruiting bodies of the cultivating medicinal mushroom Hericium erinaceus MFTCCB 134. Cold and hot water extracts (CWE, HWE) were obtained and purified, and followed by alkali extraction from the reminder solids. The composition and structure of the fractions were analysed by FTIR spectroscopy, and neutral sugars/linkage analyses were determined by GC/FID and GC/MS, respectively. Galactose, fucose and glucose were found in purified CWE,\nwhile glucose predominated in purified HWE.
Klíčová slova:
Hericium erinaceus; polysaccharides; mushrooms
Plné texty jsou dostupné na jednotlivých ústavech Akademie věd ČR.
Structural analysis of polysaccharides from mushroom hericium Erinaceus mftccb 134
The aim of this research was the structural characterisation of polysaccharides isolated from fruiting bodies of the cultivating medicinal mushroom Hericium erinaceus MFTCCB 134. Cold and hot water ...
Ambient organic aerosol origin at rural background site in the Czech Republic
Lhotka, Radek
2023 - anglický
Atmospheric aerosols (AA) are ubiquitous particles in the atmosphere that influence the Earth’s climatic system, environmental interactions, and human health. Among AA, great interest is dedicated to organic aerosols (OA) since it can represent from 20 to 90% of total submicron mass. Source apportionment of OA at background sites is one of the important tasks of current air quality protection.
Klíčová slova:
organic aerosol; air quality protection; ural background site
Plné texty jsou dostupné v digitálním repozitáři NUŠL
Ambient organic aerosol origin at rural background site in the Czech Republic
Atmospheric aerosols (AA) are ubiquitous particles in the atmosphere that influence the Earth’s climatic system, environmental interactions, and human health. Among AA, great interest is dedicated to ...
How can we best eliminate pharmaceuticals from wastewater?
Bourassi, Mahdi
2023 - anglický
Persistent pharmaceutical occurrence in different lakes and rivers usually originates from live stocks, agriculture, aquaculture, households, and hospitals. The presence of these compounds in the ecosystems leads to fatal consequences. Pharmaceuticals can threaten microorganisms in the environment, either causing its deterioration or allowing pathogens to gain resistance against antibiotics and medical treatments. These occurrences in the environment questions the ability of conventional treatment to remediate pharmaceutical wastewater.
Klíčová slova:
wastewater; pharmaceuticals; membrane separation
Plné texty jsou dostupné v digitálním repozitáři NUŠL
How can we best eliminate pharmaceuticals from wastewater?
Persistent pharmaceutical occurrence in different lakes and rivers usually originates from live stocks, agriculture, aquaculture, households, and hospitals. The presence of these compounds in the ...
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